Abnormal Dopant Distribution in POCl3-Diffused N+ Emitter of Textured Silicon Solar Cells

被引:15
作者
Ok, Young-Woo [1 ]
Rohatgi, Ajeet [1 ]
Kil, Yeon-Ho [2 ]
Park, Sung-Eun [3 ]
Kim, Dong-Hwan [3 ]
Lee, Joon-Sung [4 ]
Choi, Chel-Jong [2 ,5 ]
机构
[1] Georgia Inst Technol, Sch Elect & Comp Engn, Atlanta, GA 30332 USA
[2] Chonbuk Natl Univ, Semicond Phys Res Ctr, Sch Semicond & Chem Engn, Jeonju 561756, South Korea
[3] Korea Univ, Dept Mat Sci & Engn, Seoul 136713, South Korea
[4] Hyundai Heavy Ind Co Ltd, Elect Elect Syst Div, Yongin 446716, South Korea
[5] Chonbuk Natl Univ, Dept BIN Fus Technol, Jeonju 561756, South Korea
关键词
Junction; selective chemical etching; Si interstitial; solar cells; transmission electron microscopy (TEM); PHOSPHORUS DIFFUSION; MICROSCOPY; MECHANISM; CONTACTS;
D O I
10.1109/LED.2010.2098840
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We investigated 2-D dopant distribution in a POCl3-diffused n(+) emitter formed on textured Si solar cells using transmission electron microscopy (TEM) combined with selective chemical etching. TEM and simulation results demonstrate that the convex and concave regions of a pyramid in the textured Si surface show deeper and shallower junctions, respectively. By considering a strong dependence of phosphorus (P) diffusion on the Si interstitials, the abnormal profile of n(+) emitter in the textured Si surface could be attributed to the inhomogeneous distribution of Si interstitials caused by the geometry of the pyramid texture.
引用
收藏
页码:351 / 353
页数:3
相关论文
共 18 条
[1]   GROWTH OF STACKING-FAULTS AND DISLOCATIONS INDUCED IN SILICON BY PHOSPHORUS PREDEPOSITION [J].
ARMIGLIATO, A ;
SERVIDORI, M ;
SOLMI, S ;
VECCHI, I .
JOURNAL OF APPLIED PHYSICS, 1977, 48 (05) :1806-1812
[2]   Transmission electron microscopy study of two-dimensional dopant profiling in metal-oxide-semiconductor field effect transistor test structures and devices [J].
Choi, CJ ;
Seong, TY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (04) :1525-1529
[3]   Abnormal junction profile of silicided p+/n shallow junctions:: A leakage mechanism [J].
Choi, CJ ;
Seong, TY ;
Lee, KM ;
Lee, JH ;
Park, YJ ;
Lee, HD .
IEEE ELECTRON DEVICE LETTERS, 2002, 23 (04) :188-190
[4]   Minimizing lifetime degradation associated with thermal oxidation of upright randomly textured silicon surfaces [J].
Cousins, PJ ;
Cotter, JE .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (02) :228-240
[5]   Scanning spreading resistance microscopy (SSRM) 2D carrier profiling for ultra-shallow junction characterization in deep-submicron technologies [J].
Eyben, P ;
Janssens, T ;
Vandervorst, W .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 124 :45-53
[6]   SUPERSATURATION OF SELF-INTERSTITIALS AND UNDERSATURATION OF VACANCIES DURING PHOSPHORUS DIFFUSION IN SILICON [J].
FAHEY, P ;
DUTTON, RW ;
HU, SM .
APPLIED PHYSICS LETTERS, 1984, 44 (08) :777-779
[7]   Effect of Ag particle size in thick-film Ag paste on the electrical and physical properties of screen printed contacts and silicon solar cells [J].
Hilali, MM ;
Nakayashiki, K ;
Khadilkar, C ;
Reedy, RC ;
Rohatgi, A ;
Shaikh, A ;
Kim, S ;
Sridharan, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (01) :A5-A11
[8]   Mechanism for the formation of Ag crystallites in the Ag thick-film contacts of crystalline Si solar cells [J].
Hong, Kyoung-Kook ;
Cho, Sung-Bin ;
You, Jae Sung ;
Jeong, Ji-Weon ;
Bea, Seung-Mook ;
Huh, Joo-Youl .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (6-7) :898-904
[9]   ON MODELS OF PHOSPHORUS DIFFUSION IN SILICON [J].
HU, SM ;
FAHEY, P ;
DUTTON, RW .
JOURNAL OF APPLIED PHYSICS, 1983, 54 (12) :6912-6922
[10]   Texturing industrial multicrystalline silicon solar cells [J].
Macdonald, DH ;
Cuevas, A ;
Kerr, MJ ;
Samundsett, C ;
Ruby, D ;
Winderbaum, S ;
Leo, A .
SOLAR ENERGY, 2004, 76 (1-3) :277-283