Effects of hydrogen annealing temperature on the structural and physical properties of In1.925Cr0.05Cu0.025O3 thin films

被引:7
作者
Baqiah, H. [1 ]
Ibrahim, N. B. [2 ]
Shaari, A. H. [3 ]
Al-Hada, Naif Mohammed [1 ]
Talib, Z. A. [4 ]
机构
[1] Dezhou Univ, Shandong Key Lab Biophys, Inst Biophys, 566 Univ Rd, Dezhou, Shandong, Peoples R China
[2] Univ Kebangsaan Malaysia, Sch Appl Phys, Fac Sci & Technol, Ukm Bangi 43600, Selangor, Malaysia
[3] Univ Putra Malaysia, Dept Phys, Fac Sci, Upm Serdang 43400, Selangor, Malaysia
[4] Jeonbuk Natl Univ, Dept Phys, Coll Nat Sci, 567 Baekje Daero, Jeonju Si 54896, Jeollabuk Do, South Korea
关键词
Hydrogen annealing; Cu doped In1.95Cr0.05O3; Semiconducting behavior; Urbach energy; Oxygen defects; Magnetic behavior; DOPED IN2O3; OPTICAL-PROPERTIES; MAGNETIC-PROPERTIES; FERROMAGNETISM; ZNO; ITO;
D O I
10.1016/j.physb.2021.413290
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The structural, optical, electrical and magnetic properties of In1.95Cr0.05Cu0.025O3 thin film annealed in hydrogen at different temperature (T-H = 300, 400, 500, and 600 degrees C) were investigated. The film was amorphous at T-H = 300 degrees C and had single phase In2O3 at T-H = 400 degrees C, while mixed phases of In2O3, In and CuCr2O4 were observed at T-H = 500 and 600 degrees C. At T-H = 400 degrees C the film showed semiconducting like behavior. The film's transparency decreased with increasing T-H, and optical band gap decreased from 3.67 eV for film annealed at T-H = 400 degrees C to 3.0 eV for film annealed at T-H = 600 degrees C. The magnetization increased for film annealed at T-H = 400 and 500 degrees C while it disappeared at T-H = 600 degrees C. The structural and physical properties were discussed and compared with that for film annealed in air at T-Air = 500 degrees C.
引用
收藏
页数:8
相关论文
共 35 条
[1]   Band gap narrowing and fluorescence properties of nickel doped SnO2 nanoparticles [J].
Ahmed, Arham S. ;
Muhamed, Shafeeq M. ;
Singla, M. L. ;
Tabassum, Sartaj ;
Naqvi, Alim H. ;
Azam, Ameer .
JOURNAL OF LUMINESCENCE, 2011, 131 (01) :1-6
[2]   Ferromagnetic order in substitutional Fe-doped In2O3 powder [J].
Alshammari, M. S. ;
Alhathlool, R. ;
Al-Anzi, A. Z. ;
Museery, K. Y. ;
Alkhunayfir, M. A. ;
Lemine, O. M. ;
Bououdina, M. .
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2019, 108 :253-256
[3]   Microstructural, Electrical, Optical and Magnetic Properties of Fe- and Cu-Doped In1.95Cr0.05O3Thin Films Synthesised by Sol-Gel Method [J].
Baqiah, H. ;
Ibrahim, N. B. ;
Shaari, A. H. ;
Talib, Z. A. .
JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, 2020, 33 (11) :3535-3543
[4]   Conducting mechanisms and magnetic behaviours of Fe-doped In2O3 nanocrystalline films [J].
Baqiah, H. ;
Ibrahim, N. B. ;
Halim, S. A. ;
Talib, Z. A. ;
Flaifel, M. H. ;
Abdi, M. H. .
RESULTS IN PHYSICS, 2017, 7 :1115-1121
[5]   Physical properties of Fe doped In2O3 magnetic semiconductor annealed in hydrogen at different temperature [J].
Baqiah, H. ;
Ibrahim, N. B. ;
Halim, S. A. ;
Chen, S. K. ;
Lim, K. P. ;
Kechik, M. M. Awang .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2016, 401 :102-107
[6]   The role of cobalt doping on magnetic and optical properties of indium oxide nanostructured thin film prepared by sol-gel method [J].
Baqiah, H. ;
Ibrahim, N. B. ;
Halim, S. A. ;
Flaifel, Moayad Husein ;
Abdi, M. H. .
MATERIALS RESEARCH BULLETIN, 2015, 63 :147-154
[7]   Electrical transport, microstructure and optical properties of Cr-doped In2O3 thin film prepared by sol-gel method [J].
Baqiah, H. ;
Ibrahim, N. B. ;
Abdi, M. H. ;
Halim, S. A. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 575 :198-206
[8]   Hydrogen on In2O3: Reducibility, Bonding, Defect Formation, and Reactivity [J].
Bielz, Thomas ;
Lorenz, Harald ;
Jochum, Wilfrid ;
Kaindl, Reinhard ;
Klauser, Frederik ;
Kloetzer, Bernhard ;
Penner, Simon .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (19) :9022-9029
[9]   High mobility transparent conducting oxides for thin film solar cells [J].
Calnan, S. ;
Tiwari, A. N. .
THIN SOLID FILMS, 2010, 518 (07) :1839-1849
[10]   Donor impurity band exchange in dilute ferromagnetic oxides [J].
Coey, JMD ;
Venkatesan, M ;
Fitzgerald, CB .
NATURE MATERIALS, 2005, 4 (02) :173-179