Separation of Benzene-Isooctane Mixtures Using Poly(Vinyl Alcohol) / Graphene Composite Pervaporation Membranes

被引:0
作者
Gulhane, Harshala [1 ]
Murthy, Z. V. P. [1 ]
机构
[1] SV Natl Inst Technol, Dept Chem Engn, Surat 395007, Gujarat, India
来源
JOURNAL OF POLYMER MATERIALS | 2017年 / 34卷 / 02期
关键词
Pervaporation; Poly(vinyl alcohol); Graphene; Benzene-isooctane mixture; OPERATING-CONDITIONS; HEPTANE MIXTURES; GRAPHITE OXIDE; DEHYDRATION; PERFORMANCE; NANOSHEETS; REDUCTION;
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(vinyl alcohol)/graphene composite membranes were prepared and used in pervaporation to separate benzene-isooctane mixtures. The prepared membranes were characterized by SEM, XRD, FTIR, TGA, degree of swelling and contact angle to examine properties of composite membranes. The performance of the poly(vinyl alcohol)/graphene membranes was studied for the feed composition range 15-60 wt% benzene at different temperatures (45-60 degrees C). The optimized membrane separation performance was reported in terms of flux (1.28 g m(-2) h(-1)), selectivity (48.66) and pervaporation separation index (61.21) at 60 degrees C. The maximum percentage of benzene in permeate was 89.57% at 15 wt% benzene in feed solution.
引用
收藏
页码:439 / 453
页数:15
相关论文
共 21 条
[1]   Dehydration of acetic acid by pervaporation using SPEK-C/PVA blend membranes [J].
Chen, Jian Hua ;
Liu, Qing Lin ;
Zhu, Ai Mei ;
Zhang, Qiu Gen .
JOURNAL OF MEMBRANE SCIENCE, 2008, 320 (1-2) :416-422
[2]   Synthesis and Characterization of Metal (Pt, Pd and Fe)-graphene Composites [J].
Chen, Ming-Liang ;
Park, Chong-Yeon ;
Choi, Jong-Geun ;
Oh, Won-Chun .
JOURNAL OF THE KOREAN CERAMIC SOCIETY, 2011, 48 (02) :147-151
[3]   Graphene-based Composite Thin Films for Electronics [J].
Eda, Goki ;
Chhowalla, Manish .
NANO LETTERS, 2009, 9 (02) :814-818
[4]   Practical Chemical Sensors from Chemically Derived Graphene [J].
Fowler, Jesse D. ;
Allen, Matthew J. ;
Tung, Vincent C. ;
Yang, Yang ;
Kaner, Richard B. ;
Weiller, Bruce H. .
ACS NANO, 2009, 3 (02) :301-306
[5]   Preparation and pervaporation performance of surface crosslinked PVA/PES composite membrane [J].
Guo, Ruili ;
Fang, Xin ;
Wu, Hong ;
Jiang, Zhongyi .
JOURNAL OF MEMBRANE SCIENCE, 2008, 322 (01) :32-38
[6]   Supraparamagnetic, Conductive, and Processable Multifunctional Graphene Nanosheets Coated with High-Density Fe3O4 Nanoparticles [J].
He, Hongkun ;
Gao, Chao .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (11) :3201-3210
[7]   Pervaporation study of aqueous ethanol solution through zeolite-incorporated multilayer poly(vinyl alcohol) membranes: Effect of zeolites [J].
Huang, Z ;
Guan, HM ;
Tan, WL ;
Qiao, XY ;
Kulprathipanja, S .
JOURNAL OF MEMBRANE SCIENCE, 2006, 276 (1-2) :260-271
[8]   Pervaporation separation of toluene/n-heptane mixtures using a MSE-modified membrane: Effects of operating conditions [J].
Iravaninia, Mona ;
Mirfendereski, Mojtaba ;
Mohammadi, Toraj .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 2012, 90 (3A) :397-408
[9]   Fabrication and characterization of poly (vinyl alcohol)/chitosan blend nanofibers produced by electrospinning method [J].
Jia, Yong-Tang ;
Gong, Jian ;
Gu, Xiao-Hua ;
Kim, Hark-Yong ;
Dong, Jiong ;
Shen, Xin-Yuan .
CARBOHYDRATE POLYMERS, 2007, 67 (03) :403-409
[10]   SEPARATION OF BENZENE NORMAL-HEPTANE MIXTURES BY PERVAPORATION WITH ELASTOMERIC MEMBRANES .1. PERFORMANCE OF MEMBRANES [J].
LARCHET, C ;
BRUN, JP ;
GUILLOU, M .
JOURNAL OF MEMBRANE SCIENCE, 1983, 15 (01) :81-96