Research on high cetane and high octane number fuels and the mechanism for their common oxidation and auto-ignition

被引：44
作者：
Han, Wei-Qiang [1 ,2 ]
Yao, Chun-De [1 ]
机构：
[1] Tianjin Univ, State Key Lab Engines, Tianjin 300072, Peoples R China
[2] Xi Hua Univ, Lab IC Engine, Chengdu 610039, Peoples R China
来源：
FUEL | 2015年 / 150卷
关键词：
High cetane number fuel; High octane number fuel; Auto-ignition mechanism; Ignition characteristics of mixed fuels; LOW-TEMPERATURE COMBUSTION; HIGH-PRESSURE; KINETIC MECHANISM; ENGINE COMBUSTION; SOYBEAN BIODIESEL; DIMETHYL ETHER; PLUS O-2; MODEL; ETHANOL; AUTOIGNITION;
D O I：
10.1016/j.fuel.2015.01.090
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
This paper first of all summarized the auto-ignition mechanism of high cetane and high octane number fuels from the aspect of chemical reaction kinetics with the main purpose of explaining different auto-ignition characteristics of the two kinds of fuel and providing a classification of fuels with the same ignition principles. High cetane number fuels cover major real compression-ignition internal combustion engine fuels and references fuels in use, including straight-chain alkanes, straight-chain ethers, straight-chain esters and cetane number improvers while high octane number fuels cover major real spark-ignition internal combustion engine fuels and references fuels in use, including hydrogen, carbon monoxide, small molecular alkanes, small molecular ethanol, branched alkanes, cycloalkanes, light olefins, simple aromatic hydrocarbons and gasoline antiknock branched ethers. On this basis, 8 representative high octane number fuels were selected for mixing with the high cetane number fuel n-heptane to study the ignition characteristics of mixed fuels in order to find mechanism and corresponding rules. (C) 2015 Elsevier Ltd. All rights reserved.
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页码：29 / 40
页数：12
相关论文
共 58 条
[1]  
Alzueta MU, 2000, INT J CHEM KINET, V32, P498, DOI 10.1002/1097-4601(2000)32:8<498::AID-KIN8>3.0.CO
[2]  
2-H
[3]   Co-oxidation in the auto-ignition of primary reference fuels and n-heptane/toluene blends [J].
Andrae, J ;
Johansson, D ;
Björnbom, P ;
Risberg, P ;
Kalghatgi, G .
COMBUSTION AND FLAME, 2005, 140 (04) :267-286
[4]  
[Anonymous], COMBUSTION CHEM
[5]   Detailed chemical kinetic models for the low-temperature combustion of hydrocarbons with application to gasoline and diesel fuel surrogates [J].
Battin-Leclerc, F. .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2008, 34 (04) :440-498
[6]   Experimental Confirmation of the Low-Temperature Oxidation Scheme of Alkanes [J].
Battin-Leclerc, Frederique ;
Herbinet, Olivier ;
Glaude, Pierre-Alexandre ;
Fournet, Rene ;
Zhou, Zhongyue ;
Deng, Liulin ;
Guo, Huijun ;
Xie, Mingfeng ;
Qi, Fei .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (18) :3169-3172
[7]   Comparative modelling study on the inhibiting effect of TAME, ETBE and MTBE at low temperature [J].
Böhm, H ;
Baronnet, F ;
El Kadi, B .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (09) :1929-1933
[8]   Kinetic analysis for HO2 addition to ethylene, propene, and isobutene, and thermochemical parameters of alkyl hydroperoxides and hydroperoxide alkyl radicals [J].
Chen, CJ ;
Bozzelli, JW .
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (21) :4997-5012
[9]   Low-temperature oxidation of MTBE in a high-pressure jet-stirred flow reactor [J].
Ciajolo, A ;
DAnna, A ;
Kurz, M .
COMBUSTION SCIENCE AND TECHNOLOGY, 1997, 123 (1-6) :49-61
[10]  
Combustion Kinetics Laboratory University of Southern California, AER MECH ENG
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