Impact collision ion scattering spectroscopy (ICISS) and neutral impact collision ion scattering spectroscopy (NICISS) at surfaces of organic liquids

被引:97
作者
Andersson, G [1 ]
Morgner, H [1 ]
机构
[1] Univ Witten Herdecke, Inst Expt Phys, D-58448 Witten, Germany
关键词
alkanes; carbon; fomblin; hydroxipropionitrile; iodine; ion scattering spectroscopy; liquid surfaces; low energy ion scattering (LEIS); methylsulfolane; nitrogen; tetrabutylammoniumiodide;
D O I
10.1016/S0039-6028(98)00062-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
NICISS and ICISS in the low energy regime (1-5 keV) with helium as a projectile is used to investigate surfaces of organic liquids. We determine qualitatively the composition of the outermost layer with ICISS. The composition of the bulk near to the surface is determined quantitatively with NICISS up to a depth of several 10 Angstrom. The additional loss of energy of the projectiles by low angle scattering and electronic excitation (stopping power) is used to determine the depth of the target atom. We have investigated pure liquids as well as solutions with surface active solutes. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:138 / 151
页数:14
相关论文
共 19 条
[1]  
[Anonymous], 1977, HELIUM STOPPING POWE
[2]   INELASTIC PROCESSES IN ION-SCATTERING SPECTROSCOPY OF SOLID-SURFACES [J].
AONO, M ;
SOUDA, R .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1987, 27 (01) :55-64
[3]   On the alpha particles of radium, and their loss of range in passing through various atoms and molecules [J].
Bragg, W. H. ;
Elder, M. A. .
PHILOSOPHICAL MAGAZINE, 1905, 10 (55-60) :318-340
[4]  
DAUBERT TE, 1989, PHYSICAL THERMODYNAM
[5]   THE CONCENTRATION-DEPTH PROFILE AT THE SURFACE OF A SOLUTION OF TETRABUTYLAMMONIUM IODIDE IN FORMAMIDE, BASED ON ANGLE-RESOLVED PHOTOELECTRON-SPECTROSCOPY [J].
ESCHEN, F ;
HEYERHOFF, M ;
MORGNER, H ;
VOGT, J .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1995, 7 (10) :1961-1978
[6]  
Hagstrum H.D., 1977, Inelastic Ion-Surface Collisions, VVolume 1
[7]  
HEILAND W, 1977, INELASTIC ION SURFAC
[8]   MIES investigation of alkanethiol monolayers self-assembled on Au(111) and Ag(111) surfaces [J].
Heinz, B ;
Morgner, H .
SURFACE SCIENCE, 1997, 372 (1-3) :100-116
[9]   SURFACE SEGREGATION OF TETRA-N-ALKYLAMMONIUM HALIDES IN FORMAMIDE INVESTIGATED BY ANGLE RESOLVED ELECTRON-SPECTROSCOPY [J].
HOLMBERG, S ;
YUAN, ZC ;
MOBERG, R ;
SIEGBAHN, H .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1988, 47 :27-38
[10]  
KLEMENC A, 1960, LANDOLTBORNSTEIN 2A, V2