Transient two-liquid electroosmotic flow with electric charges at the interface

被引:67
作者
Gao, YD [1 ]
Wong, TN [1 ]
Yang, C [1 ]
Ooi, KT [1 ]
机构
[1] Nanyang Technol Univ, Sch Mech & Aerosp Engn, Singapore 639798, Singapore
关键词
two-liquid stratified flow; electric double layer; electroosrnotic pump; Laplace transform; Gaver-Stehfest method;
D O I
10.1016/j.colsurfa.2005.05.068
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The transient aspects of two-liquid electroosmotic (EO) flow are analytically studied, in which a low EO mobility liquid is delivered by the interfacial viscous force of a high EO mobility liquid driven by electroosmosis. The flow of the two liquids depends on the coupling effects between them, which involve the electrokinetic effect. The model accounts for surface charges at the liquid-liquid interface. Due to the presence of the surface charges, the shear stress is not continuous at the interface. Analytical solution of such transient two-liquid flow in rectangular channel is presented by Laplace transform method. The effects of dynamic viscosity ratio, interface potential, kinematic viscosity ratio and parameter of the electric double layer are analyzed to characterize the flow. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:117 / 128
页数:12
相关论文
共 18 条
[1]  
Brask A, 2003, NANOTECH 2003, VOL 1, P190
[2]   ELECTROKINETIC FLOW IN ULTRAFINE CAPILLARY SLITS [J].
BURGREEN, D ;
NAKACHE, FR .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (05) :1084-&
[3]   An improved method of determining the ζ-potential and surface conductance [J].
Erickson, D ;
Li, DQ ;
Werner, C .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 232 (01) :186-197
[4]   Two-fluid electroosmotic flow in microchannels [J].
Gao, YD ;
Wong, TN ;
Yang, C ;
Ooi, KT .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 284 (01) :306-314
[5]  
GORANOVIC G, 2003, THESIS TU DENMARK
[6]   An electrical suspension method for measuring the electric charge on small silicone oil droplets dispersed in aqueous solutions [J].
Gu, YG ;
Li, DQ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 195 (02) :343-352
[7]  
HUNTER RJ, 1981, PRINCIPLE APPL
[8]   Transient electrokinetic flow in fine capillaries [J].
Keh, HJ ;
Tseng, HC .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 242 (02) :450-459
[9]   THEORY OF ELECTROKINETIC FLOW IN FINE CYLINDRICAL CAPILLARIES AT HIGH ZETA-POTENTIALS [J].
LEVINE, S ;
MARRIOTT, JR ;
NEALE, G ;
EPSTEIN, N .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1975, 52 (01) :136-149
[10]  
Maillet D, 2000, Thermal Quadrupoles: solving the heat equation through integral transforms