A new family of spin-crossover complexes based on a FeII(tetrazolyl)4(MeCN)2-type core

被引：39
作者：
Bialonska, Agata [1 ]
Bronisz, Robert [1 ]
Weselski, Marek [1 ]
机构：
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
INORGANIC CHEMISTRY | 2008年 / 47卷 / 11期
关键词：
D O I：
10.1021/ic8002993
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A bitopic ligand 2-hydroxy-1-(tetrazol-1-yl)-3-(tetrazol-2-yl)propane (12pbtzOH) was synthesized and reacted with Fe(CIO4)2 center dot 6H(2)O, giving a 1D coordination polymer {[Fe(12pbtzOH)(2)(CH3CN)(2)](CIO4)(2)center dot 2CH(3)CN}(infinity) that exhibits a high-spin to low-spin transition (T1/2 down arrow = T-1/2 up arrow congruent to 104 K),. This is an unprecedented example of an iron(II) complex containing Fe(tetrazolyl)(4)(MeCN)(2) cores.
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收藏
页码：4436 / 4438
页数：3
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