Intermolecular tandem Pd-catalyzed cross-coupling [4+4] and [4+2] cycloadditions: A one-pot, five-component assembly of bicyclo[6.4.0]dodecanes

被引：54

作者：

Lee, PH ^{[1
]}

Lee, K ^{[1
]}

机构：

[1] Kangwon Natl Univ, Dept Chem, Chunchon 200701, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 21期

关键词：

cross-coupling; cycloaddition; indium; palladium; tandem reactions;

D O I：

10.1002/anie.200461957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Starting from α-bromovinylarenes, propargyl bromides, and dienophiles, a novel intermolecular tandem Pd-catalyzed cross-coupling/[4+4] and [4+2] cycloaddition sequence provides bicyclo[6.4.0]dodecane derivatives by a rapid synthesis in one reaction vessel. Five components are assembled into one molecule in this process. EWG = electronwithdrawing group. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3253 / 3256

页数：4

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