Study of Ta-barrier and pore sealing dielectric layer interaction for enhanced barrier performance of Cu/ultralow κ(κ<2.2) interconnects

被引:9
作者
Chen, XT [1 ]
Gui, D
Chi, DZ
Wang, WD
Babu, N
Hwang, N
Lo, GQ
Kumar, R
Balasubramanian, N
Kwong, DL
机构
[1] Inst Microelect, Singapore 117685, Singapore
[2] Inst Mat Res & Engn, Singapore 117602, Singapore
关键词
diffusion barriers; electric breakdown; interconnects; pore-sealing; porous dielectrics; ultralow kappa;
D O I
10.1109/LED.2005.854384
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
For Cu/ultralow kappa application, understanding of interfacial interaction between Ta and pore-sealing layer over porous dielectric is very important in order to achieve a good barrier performance. However, characterizing the effect of pore-sealing layer on barrier performance poses a big challenge. Most studies monitored degradation of the electrical performance of the Ta barrier after integration process with little discussions on interfacial interaction. In this letter, the interaction at the interface between Ta and pore-sealing layer deposited over porous SiLK (kappa similar to 2.2) film is investigated. The barrier performance is improved significantly by nitrogen incorporation during liner growth. This methodology is very effective for improving metal barrier and pore-sealing performance for Cu/ultralow kappa interconnects.
引用
收藏
页码:616 / 618
页数:3
相关论文
共 12 条
[1]  
ABELL T, 2002, P ADV MET C, P717
[2]  
[Anonymous], 2004, INT TECHNOLOGY ROADM
[3]   Post patterning meso porosity creation: A potential solution for pore sealing [J].
Caluwaerts, R ;
Van Hove, M ;
Beyer, G ;
Hoofman, RJOM ;
Struyf, H ;
Verheyden, GJAM ;
Waeterloos, J ;
Tokei, Z ;
Iacopi, F ;
Carbonell, L ;
Le, QT ;
Das, A ;
Vos, I ;
Demuynck, S ;
Maex, K .
PROCEEDINGS OF THE IEEE 2003 INTERNATIONAL INTERCONNECT TECHNOLOGY CONFERENCE, 2003, :242-244
[4]   Suppress copper diffusion through barrier metal-free structure by implantation of nitrogen atom into low-k material [J].
Deng, IC .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2003, 42 (03) :1185-1191
[5]   Dependence of the minimal PVD TA(N) sealing thickness on the porosity of Zirkon™ LK dielectric films [J].
Iacopi, F ;
Zistl, C ;
Jehoul, C ;
Tokei, Z ;
Le, QT ;
Das, A ;
Sullivan, C ;
Prokopowicz, G ;
Gronbeck, D ;
Gallagher, M ;
Calvert, J ;
Maex, K .
MICROELECTRONIC ENGINEERING, 2002, 64 (1-4) :351-360
[6]   Properties of porous HSQ-based films capped by plasma enhanced chemical vapor deposition dielectric layers [J].
Iacopi, F ;
Baklanov, MR ;
Sleeckx, E ;
Conrad, T ;
Bender, H ;
Meynen, H ;
Maex, K .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2002, 20 (01) :109-115
[7]   Factors affecting an efficient sealing of porous low-k dielectrics by physical vapor deposition Ta(N) thin films [J].
Iacopi, F ;
Tokei, Z ;
Le, QT ;
Shamiryan, D ;
Conard, T ;
Brijs, B ;
Kreissig, U ;
Van Hove, M ;
Maex, K .
JOURNAL OF APPLIED PHYSICS, 2002, 92 (03) :1548-1554
[8]   Low dielectric constant materials for microelectronics [J].
Maex, K ;
Baklanov, MR ;
Shamiryan, D ;
Iacopi, F ;
Brongersma, SH ;
Yanovitskaya, ZS .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (11) :8793-8841
[9]  
OCONNER DJ, SURFACE ANAL METHODS, V23, P107
[10]   Probing diffusion barrier integrity on porous silica low-k thin films using positron annihilation lifetime spectroscopy [J].
Sun, JN ;
Gidley, DW ;
Dull, TL ;
Frieze, WE ;
Yee, AF ;
Ryan, ET ;
Lin, S ;
Wetzel, J .
JOURNAL OF APPLIED PHYSICS, 2001, 89 (09) :5138-5144