Synthesis and characterization of complexes of UO2(II) and Th(IV) of bis-schiff bases derived from furoylpyrazolone

被引：11

作者：

Zheng, GX ^{[1
]}

Wang, QF

Luo, SG

机构：

[1] Jinan Univ, Dept Chem Engn, Jinan 250022, Peoples R China

[2] China Inst Atom Energy, Beijing 102413, Peoples R China

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2003年 / 258卷 / 03期

关键词：

D O I：

10.1023/B:JRNC.0000011773.27858.f4

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Four new complexes of UO2(II) and Th(W) with bis-Schiff bases, derived from N,N'-bis[(I-phenyl-3-methyl-5-oxo-4-pyrazolinyl)-alpha-furylmethylidyne]-1,2-propylenediimine [1,2-BPMOPFP-H-2] and N,N'-bis[(I-phenyl-3-methyl-5-oxo-4-pyrazolinyl)-alpha-furylmethylidyne]-1,3-propylenediimine [1,3-BPMOPFP-H-2], were synthesized and characterized by elemental analysis, IR, UV, (HNMR)-H-1 spectroscopy, and molar conductivity. The general formula of the complexes was confirmed to be [UO2(BPMOPFP)], [Th(BPMOPFP)(NO3)]NO3. A possible structure for the complexes have been proposed.

引用

页码：693 / 696

页数：4

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