Synthesis and characterization of complexes of UO2(II) and Th(IV) of bis-schiff bases derived from furoylpyrazolone

被引：11
|
作者：
Zheng, GX [1 ]
Wang, QF
Luo, SG
机构：
[1] Jinan Univ, Dept Chem Engn, Jinan 250022, Peoples R China
[2] China Inst Atom Energy, Beijing 102413, Peoples R China
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2003年 / 258卷 / 03期
关键词：
D O I：
10.1023/B:JRNC.0000011773.27858.f4
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Four new complexes of UO2(II) and Th(W) with bis-Schiff bases, derived from N,N'-bis[(I-phenyl-3-methyl-5-oxo-4-pyrazolinyl)-alpha-furylmethylidyne]-1,2-propylenediimine [1,2-BPMOPFP-H-2] and N,N'-bis[(I-phenyl-3-methyl-5-oxo-4-pyrazolinyl)-alpha-furylmethylidyne]-1,3-propylenediimine [1,3-BPMOPFP-H-2], were synthesized and characterized by elemental analysis, IR, UV, (HNMR)-H-1 spectroscopy, and molar conductivity. The general formula of the complexes was confirmed to be [UO2(BPMOPFP)], [Th(BPMOPFP)(NO3)]NO3. A possible structure for the complexes have been proposed.
引用
收藏
页码：693 / 696
页数：4
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