Facile synthesis of a novel BaSnO3/MXene nanocomposite by electrostatic self-assembly for efficient photodegradation of 4-nitrophenol

被引:51
作者
Chen, Shu [1 ]
Liu, Rui [3 ]
Kuai, Zeyuan [1 ]
Li, Xuezhi [1 ]
Lian, Shanshan [1 ]
Jiang, Donglin [1 ]
Tang, Jianfeng [1 ]
Li, Ling [1 ]
Wu, Ruoxi [2 ]
Peng, Chang [1 ]
机构
[1] Hunan Agr Univ, Coll Chem & Mat Sci, Changsha 410128, Hunan, Peoples R China
[2] Hunan Univ, Coll Civil Engn, Dept Water Sci & Engn, Changsha 410082, Hunan, Peoples R China
[3] Hunan Univ, Sch Phys & Elect Sci, Changsha 410082, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
MXene; BaSnO3; Photocatalyst; Degradation; 4-Nitrophenol; REDUCED GRAPHENE OXIDE; PHOTOCATALYTIC DEGRADATION; SUPERCAPACITIVE BEHAVIOR; MSNO3; M; MXENE; COMPOSITE; DYE; NANOPARTICLES; FABRICATION; ADSORPTION;
D O I
10.1016/j.envres.2021.111949
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Photocatalysis is regarded as one of the most effective strategies for the removal of the toxic organic pollutants from aqueous solutions. However, a lack of the efficient photocatalysts prevents the widespread practical application. Herein, the electrostatic self-assembly method has been designed for facile synthesis of a novel BaSnO3/PDDA/MXene (BSO/P/MX) nanocomposite as high efficient photocatalyst. In this nanocomposite, the BaSnO3 (BSO), poly (dimethyl-diallylammonium chloride) (PDDA) and MXene (Ti3C2Tx) act as the active species, structure stabilizer and efficient electron transfer medium, respectively. Due to the strong synergy of the nanocomposite, the electron-transferring ability as well as the charge separation efficiency is boosted and thus high catalytic activity achieves towards the photodegradation of 4-nitrophenol. The superior degradation rate of 98.8% and a rate constant K of 0.09113 min(-1) have been realized within 75 min of ultraviolet (UV) light irradiation over the BSO/P/MX-8% catalyst. This as-prepared nanocomposite with the excellent catalytic activity can be employed as a promising photocatalyst for treating the organic pollutants from aqueous solutions.
引用
收藏
页数:8
相关论文
共 49 条
[1]   High performance and ultrafast reduction of 4-nitrophenol using metal-organic frameworks [J].
Abdelhamid, Hani Nasser .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2021, 9 (01)
[2]   Effect of Synthesis on Performance of MXene/Iron Oxide Anode Material for Lithium-Ion Batteries [J].
Ali, Adnan ;
Hantanasirisakul, Kanit ;
Abdala, Ahmed ;
Urbankowski, Patrick ;
Zhao, Meng-Qang ;
Anasori, Babak ;
Gogotsi, Yury ;
Aissa, Brahim ;
Mahmoud, Khaled A. .
LANGMUIR, 2018, 34 (38) :11325-11334
[3]   Ag3PO4/Ti3C2 MXene interface materials as a Schottky catalyst with enhanced photocatalytic activities and anti-photocorrosion performance [J].
Cai, Tao ;
Wang, Longlu ;
Liu, Yutang ;
Zhang, Shuqu ;
Dong, Wanyue ;
Chen, Hui ;
Yi, Xuanying ;
Yuan, Jili ;
Xia, Xinnian ;
Liu, Chengbin ;
Luo, Shenglian .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 239 :545-554
[4]   Graphene nanosheets-tungsten oxides composite for supercapacitor electrode [J].
Cai, Yun ;
Wang, Yan ;
Deng, Shaojuan ;
Chen, Gang ;
Li, Qing ;
Han, Bingqian ;
Ha, Rong ;
Wang, Yude .
CERAMICS INTERNATIONAL, 2014, 40 (03) :4109-4116
[5]   2D/2D Heterojunction of Ultrathin MXene/Bi2WO6 Nanosheets for Improved Photocatalytic CO2 Reduction [J].
Cao, Shaowen ;
Shen, Baojia ;
Tong, Tong ;
Fu, Junwei ;
Yu, Jiaguo .
ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (21)
[6]   Photocatalytic degradation of organic pollutants using TiO2-based photocatalysts: A review [J].
Chen, Dongjie ;
Cheng, Yanling ;
Zhou, Nan ;
Chen, Paul ;
Wang, Yunpu ;
Li, Kun ;
Huo, Shuhao ;
Cheng, Pengfei ;
Peng, Peng ;
Zhang, Renchuang ;
Wang, Lu ;
Liu, Hui ;
Liu, Yuhuan ;
Ruan, Roger .
JOURNAL OF CLEANER PRODUCTION, 2020, 268
[7]   Fabricating 3D porous PANI/TiO2-graphene hydrogel for the enhanced UV-light photocatalytic degradation of BPA [J].
Chen, Fangyuan ;
An, Weijia ;
Li, Yao ;
Liang, Yinghua ;
Cui, Wenquan .
APPLIED SURFACE SCIENCE, 2018, 427 :123-132
[8]   Recent progress and advances in the environmental applications of MXene related materials [J].
Chen, Junyu ;
Huang, Qiang ;
Huang, Hongye ;
Mao, Liucheng ;
Liu, Meiying ;
Zhang, Xiaoyong ;
Wei, Yen .
NANOSCALE, 2020, 12 (06) :3574-3592
[9]   Photochemical fabrication of SnO2 dense layers on reduced graphene oxide sheets for application in photocatalytic degradation of p-Nitrophenol [J].
Chen, Ying ;
Sun, Fengqiang ;
Huang, Zhijian ;
Chen, He ;
Zhuang, Zefeng ;
Pan, Zizhao ;
Long, Jinfeng ;
Gu, Fenglong .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 215 :8-17
[10]   The supercapacitive behavior and excellent cycle stability of graphene/MnO2 composite prepared by an electrostatic self-assembly process [J].
Cheng, Honghong ;
Long, Lu ;
Shu, Dong ;
Wu, Jinqing ;
Gong, Yibin ;
He, Chun ;
Kang, Zongxuan ;
Zou, Xianping .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (28) :16151-16161