Synthesis of water-soluble monotosylated ethylenediamines and their application in ruthenium and iridium-catalyzed transfer hydrogenation of aldehydes

被引：17

作者：

Zhou, Zhongqiang ^{[1
]}

Ma, Qiong

Zhang, Aiqing

Wu, Lamei

机构：

[1] S Cent Univ Nationalities, Coll Chem & Mat Sci, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2011年 / 25卷 / 12期

关键词：

monotosylated ethylenediamine; transfer hydrogenation; water; aldehyde; ASYMMETRIC TRANSFER HYDROGENATION; DEPENDENT TRANSFER HYDROGENATION; BIPHASIC TRANSFER HYDROGENATION; AQUEOUS SODIUM FORMATE; CARBONYL-COMPOUNDS; CP-ASTERISK; SELECTIVE HYDROGENATION; AROMATIC-ALDEHYDES; COMPLEXES; REDUCTION;

D O I：

10.1002/aoc.1824

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Synthesis of novel water-soluble monotosylated ethylenediamines and their application in ruthenium and iridium-catalyzed transfer hydrogenation of aldehydes are described. Various aldehydes, including electron-deficient and electron-rich variants, were reduced with high conversions and chemoselectivity using sodium formate as a hydrogen source in neat water. Copyright (c) 2011 John Wiley & Sons, Ltd.

引用

页码：856 / 861

页数：6

共 26 条

[1] The biphasic transfer hydrogenation of aldehydes and ketones with isopropanol catalyzed by water-soluble rhodium complexes
Ajjou, AN
Pinet, JL
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 214 (02) : 203 - 206
[2] TRANSITION METAL-CATALYZED TRANSFER REDUCTION OF SATURATED ALDEHYDES AND KETONES BY SODIUM FORMATE UNDER PHASE-TRANSFER CONDITIONS
BAR, R
SASSON, Y
BLUM, J
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1984, 26 (03): : 327 - 332
[3] PHASE TRANSFER-CATALYZED REDUCTION OF AROMATIC-ALDEHYDES BY AQUEOUS SODIUM FORMATE IN THE PRESENCE OF DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) - A KINETIC-STUDY
BAR, R
BAR, LK
SASSON, Y
BLUM, J
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1985, 33 (02): : 161 - 177
[4] ORGANOMETALLIC CATALYSIS IN AQUEOUS-SOLUTIONS - THE BIPHASIC TRANSFER HYDROGENATION OF ALDEHYDES CATALYZED BY WATER-SOLUBLE PHOSPHINE COMPLEXES OF RUTHENIUM, RHODIUM AND IRIDIUM
BENYEI, A
JOO, F
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1990, 58 (02): : 151 - 163
[5] Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of α,β-unsaturated substrates (PTA=1,3,5-triaza-7-phosphaadamantane)
Bolaño, S
Gonsalvi, L
Zanobini, F
Vizza, F
Bertolasi, V
Romerosa, A
Peruzzini, M
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 224 (1-2) : 61 - 70
[6] Organic Synthesis "On Water"
Chanda, Arani
Fokin, Valery V.
[J]. CHEMICAL REVIEWS, 2009, 109 (02) : 725 - 748
[7] Transfer hydrogenation of citral to citronellol with Ru complexes in the mixed solvent of water and polyethylene glycol
Cheng, Haiyang
Liu, Ruixia
Hao, Jianmin
Wang, Qiang
Yu, Yancun
Cai, Shuxia
Zhao, Fengyu
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (11) : 763 - 766
[8] pH-Dependent Catalytic Activity and Chemoselectivity in Transfer Hydrogenation Catalyzed by Iridium Complex with 4,4′-Dihydroxy-2,2′-bipyridine
Himeda, Yuichiro
Onozawa-Komatsuzaki, Nobuko
Miyazawa, Satoru
Sugihara, Hideki
Hirose, Takuji
Kasuga, Kazuyuki
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (35) : 11076 - 11081
[9] BIPHASIC REDUCTION OF UNSATURATED ALDEHYDES TO UNSATURATED ALCOHOLS BY RUTHENIUM COMPLEX-CATALYZED HYDROGEN TRANSFER
JOO, F
BENYEI, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 363 (1-2) : C19 - C21
[10] Aqueous biphasic hydrogenations
Joó, F
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) : 738 - 745

← 1 2 3 →