A new method for relative Sr determination in human teeth enamel

被引:14
作者
Alvira, Fernando C. [1 ]
Rozzi, Fernando V. Ramirez [2 ]
Torchia, Gustavo A. [1 ]
Roso, Luis [3 ]
Bilmes, Gabriel M. [1 ,4 ]
机构
[1] Ctr Invest Opt CONICET La Plata CIC, RA-1900 La Plata, Argentina
[2] CNRS, UPR2147, F-75014 Paris, France
[3] Univ Salamanca, Serv Laser, Salamanca 38008, Spain
[4] Univ Nacl La Plata, La Plata, Argentina
关键词
Laser ablation; Strontium; Calcium; Incremental lines; Enamel; STRONTIUM/CALCIUM RATIOS; SR/CA; TOOTH; SR-87/SR-86; DIET; LEAD;
D O I
10.4436/jass.89012
中图分类号
Q98 [人类学];
学科分类号
030303 ;
摘要
We present a new method to determine Sr/Ca changes in hard dental tissues based on laser ablation and spectroscopic detection. By using femtosecond Laser Induced Breakdown Spectroscopy (fs-LIBS), we micro mapped the relative amount of strontium in the enamel of three human lower third molar. We also analyzed the Sr/Ca ratio along the striae of Retzius. Results show that microlibs allows detection of variation in relative Sr/Ca ratio through enamel. The same values of Sr/Ca ratio were found along a single stria. The method has a precision better than 95% and is sensitive enough to detect Sr/Ca ratio variations among striae and within stria. Fs-LIBS generates information in a fast and simple way that can be used by non-specialists to make inferences about diet or mobility in human populations and fossil hominids.
引用
收藏
页码:153 / 160
页数:8
相关论文
共 25 条
[1]   Laser-Induced Breakdown Spectroscopy Microanalysis of Trace Elements in Homo sapiens Teeth [J].
Alvira, F. C. ;
Rozzi, F. Ramirez ;
Bilmes, G. M. .
APPLIED SPECTROSCOPY, 2010, 64 (03) :313-319
[2]  
[Anonymous], 2006, Handbook of Laser-Induced Breakdown Spectroscopy
[3]   Analysis of coupled Sr/Ca and 87Sr/86Sr variations in enamel using laser-ablation tandem quadrupole-multicollector ICPMS [J].
Balter, Vincent ;
Telouk, Philippe ;
Reynard, Bruno ;
Braga, Jose ;
Thackeray, Francis ;
Albarede, Francis .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2008, 72 (16) :3980-3990
[4]   The distribution of lead within ancient and modern human teeth: Implications for long-term and historical exposure monitoring [J].
Budd, P ;
Montgomery, J ;
Cox, A ;
Krause, P ;
Barreiro, B ;
Thomas, RG .
SCIENCE OF THE TOTAL ENVIRONMENT, 1998, 220 (2-3) :121-136
[5]   NONLINEARITY IN THE RELATIONSHIP BETWEEN BONE SR/CA AND DIET - PALEODIETARY IMPLICATIONS [J].
BURTON, JH ;
WRIGHT, LE .
AMERICAN JOURNAL OF PHYSICAL ANTHROPOLOGY, 1995, 96 (03) :273-282
[7]   Do enamel microstructures have regular time dependency? Conclusions from the literature and a large-scale study [J].
FitzGerald, CM .
JOURNAL OF HUMAN EVOLUTION, 1998, 35 (4-5) :371-386
[8]   High resolution analysis of uranium and thorium concentration as well as U-series isotope distributions in a Neanderthal tooth from Payre (Ardeche, France) using laser ablation ICP-MS [J].
Gruen, Rainer ;
Aubert, Maxime ;
Joannes-Boyau, Renaud ;
Moncel, Marie-Helene .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2008, 72 (21) :5278-5290
[9]   Femtosecond laser-induced breakdown spectroscopy:: Physics, applications, and perspectives [J].
Gurevich, E. L. ;
Hergenroeder, R. .
APPLIED SPECTROSCOPY, 2007, 61 (10) :233A-242A
[10]  
Humphrey LT, 2007, VERTEBR PALEOBIOL PA, P303, DOI 10.1007/978-1-4020-5845-5_21