Synthesis and purification of a metallic nitride fullerene BisAdduct:: Exploring the reactivity of Gd3N@C80

被引：52

作者：

Stevenson, S

Stephen, RR

Amos, TM

Cadorette, VR

Reid, JE

Phillips, JP

机构：

[1] Univ So Mississippi, Dept Chem & Biochem, Hattiesburg, MS 39406 USA

[2] Luna Innovat, Blacksburg, VA 24060 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 37期

关键词：

D O I：

10.1021/ja0535312

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This research represents initial functionalization of a Gd3N@C80 metallic nitride fullerene (MNF). Results demonstrate that a bisadduct can be prepared in an isolable yield for this MRI precursor MNF. This Gd3N@C80 bisadduct is synthesized and purified, and preliminary characterization is reported. This is a significant finding as, to date, only MNF monoadducts have been purified. Copyright © 2005 American Chemical Society.

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页码：12776 / 12777

页数：2

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