Crystal structure of quinoline-2-carboxylic acid • quinolinium-2-carboxylate

被引：31
作者：
Dobrzynska, D
Jerzykiewicz, LB
机构：
[1] Wroclaw Univ Technol, Inst Inorgan Chem & Met Rare Elements, PL-50370 Wroclaw, Poland
[2] Univ Wroclaw, Fac Chem, PL-50138 Wroclaw, Poland
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2004年 / 34卷 / 01期
关键词：
quinoline-2-carboxylic acid center dot quinolinium-2-carboxylate; tautomeric; dimers;
D O I：
10.1023/B:JOCC.0000014688.79954.ca
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Quinoline-2-carboxylic acid (quinaldic acid), C10H7NO2, crystallizes in the monoclinic space group P2(1)/c, a = 9.724(1) Angstrom, b = 5.937(1) Angstrom, c = 27.545(2) Angstrom, beta = 90.15(1)degrees, z = 4, and occurs in the crystal in two tautomeric forms: the neutral molecule and the zwitterion, with molecular ratio 1:1. The compound can be named quinoline-2-carboxylic acid . quinolinium-2-carboxylate. The crystal structure is built up of tautomeric pairs consisting of C9H6NCOOH and C9H6NH+COO- moieties, held up together by hydrogen bonds.
引用
收藏
页码：51 / 55
页数：5
相关论文
共 34 条
  • [21] Syntheses, crystal structures and properties of four novel coordination polymers assembled from versatile 1,2,3,5-benzenetetracarboxylic acid
    Wei, Chao
    Xia, Chang-Kun
    Wu, Yun-Long
    Wu, Fan
    Yang, Shen
    Ma, Jia-Li
    POLYHEDRON, 2015, 89 : 189 - 195
  • [22] Temperature-dependent dimerization of TCNQ anion-radical in [Ni (bpy)3]2(TCNQ-TCNQ)(TCNQ)2•6H2O: Single-crystal structure, magnetic and quantum chemical study
    Sterbinska, Slavomira
    Holub, Mariia
    Hegedus, Michal
    Titis, Jan
    Cizmar, Erik
    Falvello, Larry R.
    Cernak, Juraj
    SOLID STATE SCIENCES, 2022, 131
  • [23] Structure and properties of hydroxyl radical modified nucleic acid components: pairing properties of 2-hydroxyadenine and 8-oxoadenine
    Cysewski, P
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1999, 466 : 59 - 67
  • [24] Crystal structure and Hirshfeld surface analysis of 4-(2-chloroethyl)-5-methyl-1,2-dihydropyrazol-3-one
    Naghiyev, Farid N.
    Khrustalev, Victor N.
    Akkurt, Mehmet
    Dukhnovsky, Evgeny A.
    Bhattarai, Ajaya
    Khalilov, Ali N.
    Mamedov, Ibrahim G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 223 - +
  • [25] Crystal structures of (Et4N)3M2F9 (M = V, Cr, Fe) determined by X-ray single-crystal and powder diffraction:: A new structure type for A3M2X9 compounds
    Krämer, KW
    Schenker, R
    Hauser, J
    Weihe, H
    Güdel, HU
    Bürgi, HB
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (11): : 2511 - 2516
  • [26] Crystal structure and Hirshfeld surface analysis of 1-(2-amino-4-methyl-1,3-thiazol-5-yl)ethan-1-one
    Huseynov, Elnur Z.
    Akkurt, Mehmet
    Brito, Ivan
    Bhattarai, Ajaya
    Rzayev, Rovnag M.
    Asadov, Khammed A.
    Maharramov, Abel M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 890 - +
  • [27] Synthesis, crystal structure and magnetism of a two-dimensional Ni(II) coordination polymer with thiocyanate anion and dehydrogen-1,10-phenanthrolin-2-ol as bridging ligands
    Shi, Jing-Min
    Liu, Qi-Sheng
    Shi, Wei
    JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (07) : 1121 - 1126
  • [28] Crystal structure and Hirshfeld surface analysis of 2-amino-4-(4-methoxyphenyl)-6-oxo-1-phenyl-1,4,5,6-tetrahydropyridine-3-carbonitrile
    Asadov, Khammed A.
    Khrustalev, Victor N.
    Dobrokhotova, Ekaterina, V
    Akkurt, Mehmet
    Huseynova, Afet T.
    Akobirshoeva, Anzurat A.
    Huseynov, Elnur Z.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 330 - +
  • [29] Crystal structure and Hirshfeld surface analysis of 5-acetyl-2-amino-4-(4-bromonhenyl)-6-oxo-1-phenyl-1,4,5,6-tetrahydropyridine-3-carbonitrile
    Mamedov, Ibrahim G.
    Khrustalev, Victor N.
    Akkurt, Mehmet
    Novikov, Anton P.
    Asgarova, Ayten R.
    Aliyeva, Khatira N.
    Akobirshoeva, Anzurat A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 291 - +
  • [30] Crystal structure and Hirshfeld surface analysis of 3,3′-[ethane-1,2-diylbis(oxy)]bis(5,5-dimethylcyclohex-2-en-1-one) including an unknown solvate
    Sadikhova, Nurlana D.
    Akkurt, Mehmet
    Ismayilov, Valeh M.
    Yusubov, Niftali N.
    Hasanov, Khudayar I.
    Bhattarai, Ajaya
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 615 - +
1234