Tailoring properties of borohydrides for hydrogen storage: A review

被引：236

作者：

Rude, Line H. ^{[1
,3
]}

Nielsen, Thomas K. ^{[2
,3
]}

Ravnsbaek, Dorthe B. ^{[1
,3
]}

Boesenberg, Ulrike ^{[5
]}

Ley, Morten B. ^{[1
,3
]}

Richter, Bo ^{[1
,3
]}

Arnbjerg, Lene M. ^{[1
,3
]}

Dornheim, Martin ^{[5
]}

Filinchuk, Yaroslav ^{[6
,7
]}

Besenbacher, Flemming ^{[4
]}

Jensen, Torben R. ^{[1
,2
,3
]}

机构：

[1] Aarhus Univ, Interdisciplinary Nanosci Ctr, Ctr Mat Crystallog, DK-8000 Aarhus C, Denmark

[2] Aarhus Univ, Interdisciplinary Nanosci Ctr, Ctr Energy Mat, DK-8000 Aarhus C, Denmark

[3] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

[4] Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Ctr Energy Mat, DK-8000 Aarhus C, Denmark

[5] Helmholtz Zentrum Geesthacht, Inst Mat Res, D-21502 Geesthacht, Germany

[6] Swiss Norwegian Beam Lines ESRF, F-38043 Grenoble, France

[7] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, B-1348 Louvain, Belgium

来源：

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2011年 / 208卷 / 08期

基金：

新加坡国家研究基金会;

关键词：

anion substitution; hydrogen storage; metal borohydrides; nano confinement; reactive hydride composites; X-RAY-DIFFRACTION; REACTIVE HYDRIDE COMPOSITES; COMPLEX METAL-HYDRIDES; SOLID-STATE NMR; MAGNESIUM HYDRIDE; CRYSTAL-STRUCTURE; AMMONIA BORANE; ELECTROCHEMICAL HYDROGENATION; DEHYDROGENATION KINETICS; THERMAL-DECOMPOSITION;

D O I：

10.1002/pssa.201001214

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Hydrogen is recognized as a possible future energy carrier, which can be produced from renewable energy and water. A major challenge in a future 'hydrogen economy' is the development of safe, compact, robust, and efficient means of hydrogen storage, in particular for mobile applications. The present review focuses on light metal boron based hydrides, for which the general interest has expanded significantly during the past few years. Synthesis methods, physical, chemical and structural properties of novel boron based hydrides are reviewed along with new approaches for improving kinetic and thermodynamic properties: (i) anion substitution, (ii) reactive hydride composites and (iii) nanoconfinement of hydrides and chemical reactions. The light metal borohydrides reveal a fascinating structural chemistry and have the potential for storing large amounts of hydrogen. A combination of the different approaches may provide a new route to a wide range of interesting energy storage materials in the future. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1754 / 1773

页数：20

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