Hydrothermal synthesis and crystal structure of (H2bpp)3[Mo5P2O23]•H2O: a twofold interpenetrating 3D supramolecular architecture constructed of Standberg-type polyoxometalate

被引：10
作者：
Qu, Xiaoshu [1 ,2 ]
Xu, Lin [1 ]
Yang, Yanyan [1 ]
Li, Fengyan [1 ]
Guo, Weihua [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Key Lab Polyoxometalates Sci, Minist Educ, Changchun 130024, Peoples R China
[2] Jilin Inst Chem Technol, Jilin 132073, Peoples R China
来源：
STRUCTURAL CHEMISTRY | 2011年 / 22卷 / 05期
关键词：
Polyoxometalate; Hydrothermal synthesis; Supramolecular structure; Interpenetrating; ELECTRODE; COMPOUND; ANION; SALT;
D O I：
10.1007/s11224-011-9782-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel three-dimensional (3D) supramolecular assembly of Standberg-type polyoxometalate and flexible organic molecule (H(2)bpp)(3)[Mo5P2O23]center dot H2O (1) [bpp = 1,3-bis(4-pyridyl)propane] has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR spectra, elemental analysis and thermogravimetric analysis (TGA). X-ray analyses show that compound 1 represent a twofold interpenetrating 3D supramolecular architecture constructed of Standberg-type polyoxometalate and bpp molecular through the hydrogen bonds as well as electrostatic interactions.
引用
收藏
页码：965 / 969
页数：5
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