Influence of powder characteristics on the structural and the mechanical properties of additively manufactured Zr-based bulk metallic glass

被引:42
作者
Wegner, Jan [1 ]
Frey, Maximilian [2 ]
Piechotta, Markus [1 ]
Neuber, Nico [2 ]
Adam, Bastian [2 ]
Platt, Sebastian [1 ]
Ruschel, Lucas [2 ]
Schnell, Norman [1 ]
Riegler, Sascha Sebastian [2 ]
Jiang, Hao-Ran [2 ]
Witt, Gerd [1 ]
Busch, Ralf [2 ]
Kleszczynski, Stefan [1 ,3 ]
机构
[1] Univ Duisburg Essen, Chair Mfg Technol, Lotharstr 1, D-47057 Duisburg, Germany
[2] Saarland Univ, Chair Metall Mat, Campus C6-3, D-66123 Saarbrucken, Germany
[3] Ctr Nanointegrat Duisburg Essen CENIDE, Carl Benz Str 199, D-47057 Duisburg, Germany
关键词
Bulk metallic glasses; Additive manufacturing; Laser-based powder bed fusion of Metals (PBF-LB/M); Oxygen contamination; PARTICLE-SIZE; CRYSTALLIZATION BEHAVIOR; OXYGEN IMPURITY; PHASE-FORMATION; ALLOY;
D O I
10.1016/j.matdes.2021.109976
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Additive manufacturing of Zr-based bulk metallic glasses (BMGs) is subject to growing scientific and industrial attention. Laser-based powder bed fusion of metals (PBF-LB/M) becomes a key technology to overcome current restrictions of size and geometry in the manufacturing of BMGs. For industrial application, further knowledge about defect formation, such as porosity and crystallization, is mandatory to develop processing strategies and suitable quality assurance. In this context, the influence of the particle size distribution, oxygen contamination, and applied process parameters during the PBF-LB/M of the glass-forming alloy AMZ4 (in at.% Zr59.3Cu28.8Al10.4Nb1.5) on the structural and mechanical properties were evaluated. It was found that the addition of SiO2 flow aid to the feedstock is suitable to increase flowability without impeding fabrication of the amorphous material. Furthermore, the processing of partially crystalline powder particles into amorphous samples is demonstrated. It indicates that today's high effort producing amorphous powders and thus the production costs can be reduced. Flexural bending tests and high-energy synchrotron X-ray diffraction reveal that the powder feedstock's oxygen content is crucial for the amorphization, embrittlement, and flexural strength of PBF-LB/M processed Zr-based BMGs. (C) 2021 Published by Elsevier Ltd.
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页数:12
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