Facile synthesis and X-ray structures of (η5-C5Me5)Ti(OArF)3 (OArF = OC6F5,OCH2C6F5, and OCH2C6F2H3)

被引：5
作者：
Lee, Junseong
Do, Youngkyu [1 ]
Kim, Youngjo
机构：
[1] Korea Adv Inst Sci & Technol, Ctr Mol Design & Synth, Sch Mol Sci BK21, Dept Chem, Taejon 305701, South Korea
[2] Chungbuk Natl Univ, Dept Chem, Chungbuk 361763, South Korea
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 16期
关键词：
titanium; half-sandwich metallocene; X-ray structure; pentafluorophenol; pentafluorobenzylalcohol; 2,5-difluorobenzylalcohol; penta-methylcyclopentadienyl; pi-pi interaction;
D O I：
10.1016/j.jorganchem.2007.05.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New half-sandwich titanocene complexes (eta(5)-C5Me5)Ti(OC6F5)(3) (1), (eta(5)-C5Me5)Ti(OCH2C6F5)(3) (2), and (eta(5)-C5Me5)Ti(OCH2C6F2H3)(3) (3) were synthesized via the displacement of methoxide ligands in (eta(5)-C5Me5)Ti(OMe)(3) by the corresponding aryloxy or benzyloxy ligands. These compounds have been fully characterized by various spectroscopic methods including X-ray crystallography. Compound 1 has a distorted three-legged piano stool structure. However, complexes 2 and 3 have the chariot-like structure, where chariot means a two-wheeled horse-drawn vehicle. The pi electron donation of oxygen atom to Ti center in complexes 1-3 is considerable. (c) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：3593 / 3598
页数：6
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