Comprehensive GC x GC chromatography for the characterization of sulfur compound in fuels: A review

被引：44

作者：

Lorentz, Chantal ^{[1
]}

Laurenti, Dorothee ^{[1
]}

Zotin, Jose Luiz ^{[2
]}

Geantet, Christophe ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, UMR 5256, Inst Rech Catalyse & Environm Lyon,IRCELYON, 2 Ave Albert Einstein, F-69626 Villeurbanne, France

[2] Petrobras SA, R&D Ctr CENPES, Av Horacio Macedo 950, BR-21941915 Rio De Janeiro, RJ, Brazil

来源：

CATALYSIS TODAY | 2017年 / 292卷

关键词：

Comprehensive GC x GC; Fuels; Sulfide compounds; S detectors; 2-DIMENSIONAL GAS-CHROMATOGRAPHY; MASS-SPECTROMETRIC DETECTION; OXIDATIVE DESULFURIZATION; DETAILED CHARACTERIZATION; DEEP DESULFURIZATION; OILS; PETROLEUM; DIESEL; SEPARATION; SPECIATION;

D O I：

10.1016/j.cattod.2017.04.052

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Since the beginning of the 2000's, comprehensive GC x GC chromatography brought a totally new way to characterize complex matrices. This disruptive technique is well adapted to fuels and rapidly gained importance in R & D laboratories of oil (and related) companies. Therefore, this analytical tool has been applied to many aspects of refining and especially the challenge of reducing the sulfur content in fuels. The present article reviews the use of comprehensive GC x GC for understanding the nature of sulfur compounds in refinery products (from gasoline to VGO) and their catalytic conversion through various catalytic processes such as HDS, AOTS, ODS. Various types of detectors (universal or specific) as well as FIT GC x GC have been applied and can be combined in order to get a better description of the S compounds in oil products.

引用

页码：26 / 37

页数：12

共 48 条

[1] Oxidative Desulfurization Process Monitoring Using Comprehensive Two-Dimensional Gas Chromatography and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry [J].