Synthesis and spectral characterization of sparteine and α-isosparteine complexes with copper(II) sulfate

被引：5

作者：

Jasiewicz, B.

Boczon, W. L.

Kowalczyk, A.

机构：

[1] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland

[2] Polish Acad Sci, Inst Mol Phys, PL-60179 Poznan, Poland

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 22-24期

关键词：

sparteines; copper(II) coniplexes; IR and UV-Vis spectroscopy; magnetic properties; DFT calculations;

D O I：

10.1080/00958970701272110

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of CuSO4 of the general formula [Cu(C-15 H26N2)SO4] where [C-15 H26N2] is sparteine or alpha-isosparteine have been obtained from copper(II) and an appropriate alkaloid. The 1 : 1 (metal : alkaloid) stoichiometry was confirmed by elemental analysis. The compounds have been characterized by mass spectrometry, IR, and UV-Vis spectroscopy. The magnetic properties were also determined; no anti-ferromagnetic behavior was observed. Information on the geometry of newly obtained compounds wits obtained using quantum-chemical calculations.

引用

页码：2441 / 2448

页数：8

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