The paper reports the photo-induced effects on the optical and structural properties of ternary Ge30Se70-xBix (x = 5, 10) thin films illuminated with 532 nm green laser light. The material exhibits photo-bleaching nature when exposed to laser light for a prolonged time. The amorphous nature sustains after laser irradiation as detected by X-ray diffraction. The chemical composition of the deposited thin film was examined by energy dispersive X-ray analysis. Field emission scanning electron microscopy investigation showed that the surface morphology was influenced by the laser irradiation. The transmission spectra were collected from UV-Vis-NIR spectroscopy which shows the films exhibit indirect allowed transition. The other optical parameters were calculated from the transmission spectra. The linear optical properties were influenced by the laserinduced phenomena. The photobleaching is explained on the basis of homopolar bond breaking and formation of heteropolar bonds with photon energy. The Raman spectra provided the evidence of photo structural changes in the films.
机构:
CUNY City Coll, Dept Chem, New York, NY 10031 USA
INL Int Iberian Nanotechnol Lab, P-4715330 Braga, PortugalCUNY City Coll, Dept Chem, New York, NY 10031 USA
Claro, Marcel S.
;
Levy, Ido
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机构:
CUNY City Coll, Dept Chem, New York, NY 10031 USA
CUNY, PhD Program Chem, Grad Ctr, New York, NY 10016 USACUNY City Coll, Dept Chem, New York, NY 10031 USA
Levy, Ido
;
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Gangopadhyay, Abhinandan
;
Smith, David J.
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机构:
Arizona State Univ, Dept Phys, Tempe, AZ 85287 USACUNY City Coll, Dept Chem, New York, NY 10031 USA
Smith, David J.
;
Tamargo, Maria C.
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机构:
CUNY City Coll, Dept Chem, New York, NY 10031 USA
CUNY, PhD Program Chem, Grad Ctr, New York, NY 10016 USACUNY City Coll, Dept Chem, New York, NY 10031 USA
机构:
CUNY City Coll, Dept Chem, New York, NY 10031 USA
INL Int Iberian Nanotechnol Lab, P-4715330 Braga, PortugalCUNY City Coll, Dept Chem, New York, NY 10031 USA
Claro, Marcel S.
;
Levy, Ido
论文数: 0引用数: 0
h-index: 0
机构:
CUNY City Coll, Dept Chem, New York, NY 10031 USA
CUNY, PhD Program Chem, Grad Ctr, New York, NY 10016 USACUNY City Coll, Dept Chem, New York, NY 10031 USA
Levy, Ido
;
论文数: 引用数:
h-index:
机构:
Gangopadhyay, Abhinandan
;
Smith, David J.
论文数: 0引用数: 0
h-index: 0
机构:
Arizona State Univ, Dept Phys, Tempe, AZ 85287 USACUNY City Coll, Dept Chem, New York, NY 10031 USA
Smith, David J.
;
Tamargo, Maria C.
论文数: 0引用数: 0
h-index: 0
机构:
CUNY City Coll, Dept Chem, New York, NY 10031 USA
CUNY, PhD Program Chem, Grad Ctr, New York, NY 10016 USACUNY City Coll, Dept Chem, New York, NY 10031 USA