Electropolymerized Highly Photoconductive Thin Films of Cyclopalladated and Cycloplatinated Complexes

被引：25

作者：

Ionescu, Andreea ^{[1
,2
]}

Lento, Raffaella ^{[3
]}

Mastropietro, Teresa F. ^{[4
]}

Aiello, Iolinda ^{[1
,2
]}

Termine, Roberto ^{[1
,5
]}

Golemme, Attilio ^{[1
,3
,5
]}

Ghedini, Mauro ^{[1
,2
]}

Bellec, Nathalie ^{[6
]}

Pini, Elena ^{[7
]}

Rimoldi, Isabella ^{[7
]}

Godbert, Nicolas ^{[1
,2
]}

机构：

[1] Ctr Eccelenza CEMIF CAL, LASCAMM CR INSTM, Unita INSTM Calabria, I-87036 Arcavacata Di Rende, CS, Italy

[2] Univ Calabria, Dipartimento Chim & Tecnol Chim, I-87036 Arcavacata Di Rende, CS, Italy

[3] Univ Calabria, Dipartimento Fis, I-87036 Arcavacata Di Rende, CS, Italy

[4] Univ Calabria, Dipartimento Ingn Ambiente & Terr & Ingn Chim, I-87036 Arcavacata Di Rende, CS, Italy

[5] Univ Calabria, UOS Licryl Ist IMIP CNR, Dipartimento Fis, I-87036 Arcavacata Di Rende, CS, Italy

[6] Univ Rennes 1, Inst Sci Chim Rennes, CNRS, UMR 6226, F-35042 Rennes, France

[7] Univ Milan, Dipartimento Sci Farmaceut, Sez Chim Gen & Organ Marchesini, I-20133 Milan, Italy

来源：

ACS APPLIED MATERIALS & INTERFACES | 2015年 / 7卷 / 07期

关键词：

palladium(II) complexes; electropolymerization; photoconductivity; PHOTOREFRACTIVE MATERIALS; CONDUCTING POLYMERS; CHARGE-TRANSPORT; IONIC LIQUID; SOLAR-CELLS; RUTHENIUM; EFFICIENT; METALLOPOLYMER; ENHANCEMENT; COMPOSITES;

D O I：

10.1021/am506984m

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The complete characterization of novel electropolymerizable organometallic complexes is presented. These are newly synthesized cyclometalated complexes of general formula (PPy)M(O boolean AND N)(n) (H(PPy) = 2-phenylpyridine, M = Pd(II) or Pt(II), H(O boolean AND N)(n) = Schiff base). Polymeric thin films have been obtained from these complexes by electropolymerization of the triphenylamino group grafted onto the H(O boolean AND N)(n) ancillary ligand. The redox behavior and the photoconductivity of both of the monomers (PPy)M(O boolean AND N)(n) and the electropolymerized species have been investigated. The polymeric films of (PPy)M(O boolean AND N)(n) have shown a very significant enhancement of photoconductivity when compared to their monomeric amorphous counterparts. The high stability of the obtained films strongly suggests that electropolymerization of cyclometalated complexes represents a viable deposition technique of quality thin films with improved photoconduction properties, hence opening the door to a new class of materials with suitable properties for optoelectronic applications.

引用

页码：4019 / 4028

页数：10

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