Conjugated Polymer Films Having a Uniaxial Molecular Orientation and Network Structure Prepared by Electrochemical Polymerization in Liquid Crystals

被引：2

作者：

Dong, Jiuchao ^{[1
]}

Nimori, Shigeki ^{[2
]}

Goto, Hiromasa ^{[1
]}

机构：

[1] Univ Tsukuba, Fac Pure & Appl Sci, Div Mat Sci, Tsukuba, Ibaraki 3058573, Japan

[2] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050003, Japan

来源：

POLYMERS | 2021年 / 13卷 / 15期

基金：

日本学术振兴会;

关键词：

orientation; crosslink; conjugated polymers; electrochemical polymerization; liquid crystal; PHOTOVOLTAIC PROPERTIES; ELECTROPOLYMERIZATION; MORPHOLOGY; SURFACE; TRANSISTORS; POLYPYRROLE; TRANSITION; DEPOSITION; EFFICIENCY; TRANSPORT;

D O I：

10.3390/polym13152425

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new method for fabricating conjugated polymer films was developed using electrochemical polymerization in liquid crystals and magnetic orientation. A uniaxial main chain orientation and a crosslinked network structure were achieved with this method. By employing eight types of monomers, the influence of the crosslinking for the film was investigated. The crosslinking was found to improve the solvent resistance of the conjugated polymer films. This new method is expected to be useful in various applications, such as high-powered organic electronic devices with durability.

引用

页数：20

共 46 条

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