Metal-Organic Framework-Derived CuS Nanocages for Selective CO2 Electroreduction to Formate

被引：35
作者：
Zhang, Xing [1 ,2 ]
Sa, Rongjian [1 ,3 ]
Zhou, Feng [1 ,2 ]
Rui, Yuan [1 ]
Liu, Ruixia [4 ]
Wen, Zhenhai [1 ]
Wang, Ruihu [1 ,2 ,4 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Minjiang Univ, Ocean Coll, Inst Oceanog, Fuzhou 350108, Fujian, Peoples R China
[4] Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China
来源：
CCS CHEMISTRY | 2021年 / 3卷 / 12期
基金：
中国国家自然科学基金;
关键词：
copper sulfide; hollow structure; CO2; reduction; electrocatalysis; formate; CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; ELECTROCATALYTIC CONVERSION; CATALYST; MONOXIDE; METHANOL; DESIGN;
D O I：
10.31635/ccschem.020.202000589
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electroreduction of CO2 to target products with high activity and selectivity has techno-economic importance for renewable energy storage and CO2 utilization. Herein, we report a hierarchical CuS hollow polyhedron (CuS-HP) for electrocatalytic CO2 reduction (E-CO2R) in neutral pH aqueous media. Under E-CO2R conditions, CuS-HP undergoes structural reconstruction into sulfur-doped metallic Cu catalyst, which promotes formate production with Faradaic efficiency >90% in a wide potential range. The durability of the in situ evolved catalyst has been demonstrated by stable operation for 36 h at a formate partial current density of similar to 16 mA cm(-2) at -0.6 V versus reversible hydrogen electrode. Theoretical thermodynamic analysis reveals that the sulfur-doped Cu(111) facet is responsible for high formate selectivity by promoting formate production and suppressing hydrogen evolution.
引用
收藏
页码：199 / 207
页数：9
相关论文
共 50 条
[31]   Multi-metallic organic framework-derived materials for electrocatalytic CO2 reduction reaction [J].
Mensah-Darkwa, Kwadwo ;
Ampong, Daniel Nframah ;
Dzikunu, Perseverance ;
Souza, Felipe M. de ;
Kumar, Anuj ;
Gupta, Ram K. .
FUEL, 2023, 335
[32]   Multi-morphology CuS catalyst for selective electrocatalytic of CO2 conversion to formate [J].
Qi, Renzhi ;
Chen, Fuqiang ;
Zhong, Zhaoping ;
Jia, You ;
Yang, Yuxuan ;
Yun, Zekun ;
Ye, Qihang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 1008
[33]   Metal-organic framework-derived multifunctional photocatalysts [J].
Zhang, Yaping ;
Xu, Jixiang ;
Zhou, Jie ;
Wang, Lei .
CHINESE JOURNAL OF CATALYSIS, 2022, 43 (04) :971-1000
[34]   A versatile transition metal ion-binding motif derived from covalent organic framework for efficient CO2 electroreduction [J].
Zhao, Yong ;
Hao, Long ;
Ning, Jing ;
Zhu, Haijin ;
Vijayakumar, Amruthalakshmi ;
Wang, Caiyun ;
Wallace, Gordon G. .
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2021, 291
[35]   The Progress of Metal-Organic Framework for Boosting CO2 Conversion [J].
Di, Zhengyi ;
Qi, Yu ;
Yu, Xinxin ;
Hu, Falu .
CATALYSTS, 2022, 12 (12)
[36]   Metal-Organic Framework-Derived Synthesis of Cobalt Indium Catalysts for the Hydrogenation of CO2 to Methanol [J].
Pustovarenko, Alexey ;
Dikhtiarenko, Alla ;
Bavykina, Anastasiya ;
Gevers, Lieven E. M. ;
Ramirez, Adrian ;
Russkikh, Artem ;
Telalovic, Selvedin ;
Tapia, Antonio Aguilar ;
Hazemann, Jean Louis ;
Ould-Chikh, Samy ;
Gascon, Jorge .
ACS CATALYSIS, 2020, 10 (09) :5064-5076
[37]   Metal-organic framework-derived Co-C catalyst for the selective hydrogenation of cinnamaldehyde to cinnamic alcohol [J].
Tian, Fuping ;
Zhang, Xinchi ;
Sheng, Yingying ;
Chen, Xiao ;
Wang, Xiang ;
Liang, Changhai .
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2023, 62 :46-56
[38]   Combined hydrogenation of CO2 and CO to methanol using Aerosol-Assisted Metal-Organic Framework-Derived hybrid catalysts [J].
Huang, Ren-You ;
Hoang, Thanh Truc Nguyen ;
Hsueh, Yu -An ;
Tsai, De-Hao .
FUEL, 2023, 349
[39]   Ultrathin two-dimensional triptycence-based metal-organic framework for highly selective CO2 electroreduction to CO [J].
Xue, Huan ;
Zhu, Haolin ;
Huang, Jiarun ;
Liao, Peiqin ;
Chen, Xiaoming .
CHINESE CHEMICAL LETTERS, 2023, 34 (01)
[40]   Reconstructed Bismuth-Based Metal-Organic Framework Nanofibers for Selective CO2-to-Formate Conversion: Morphology Engineering [J].
Ying, Yulong ;
Khezri, Bahareh ;
Kosina, Jiri ;
Pumera, Martin .
CHEMSUSCHEM, 2021, 14 (16) :3402-3412
12345