Study on the regioselectivity of the reaction of alpha-unsaturated organozinc compounds with alpha-imino esters from 2-amino or 3-amino alcohols .3. Synthesis of 3-amino-1,5 (or 1,6)-diols, cyclization into substituted 3-prop-1-enylmorpholines and to 5-s-butyl-2,3-dihydro-6H-1,4-coxazines

被引：1

作者：

Courtois, G ^{[1
]}

Miginiac, L ^{[1
]}

机构：

[1] UNIV POITIERS,SYNTH ORGAN LAB,CNRS,URA 574,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 517卷 / 1-2期

关键词：

organic synthesis; aminodiols; allylic aminoesters; cyclization; morpholines; 2,3-dihydro-1,4-oxazines;

D O I：

10.1016/0022-328X(95)06053-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

O-silylated alpha-aminoesters, resulting from the regioselective reaction between organozinc derivatives and alpha-iminoesters hearing an alcohol group, are transformed into 3-amino-1,5 (or 1,6)-diols; then 2-allylic-3-amino-1,5-diols are converted into 3-prop-1-enylmorpholines or into 5-s-butyl-2,3-dihydro-6H-1,4-oxazines.

引用

页码：37 / 45

页数：9

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