The first μ3-oxalato-bridged copper complex with tridentate Schiff base ligand N-ethyl-N′-salicylidene-1,2-diaminoethane:: Synthesis, structure, and magnetic properties

被引：40

作者：

Bian, HD ^{[1
]}

Gu, W ^{[1
]}

Xu, JY ^{[1
]}

Bian, F ^{[1
]}

Yan, SP ^{[1
]}

Liao, DZ ^{[1
]}

Jiang, ZH ^{[1
]}

Cheng, P ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 14期

关键词：

D O I：

10.1021/ic034003z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first mu(3)-oxalato-bridged copper(II) complex, {[Cu-3(L)(3)(mu(3)-C2O4)]-[Cu(L)(H2O))(ClO4)(2)}.0.5(H2O).0.5(CH3OH), where HL = N-ethyl-N'-salicylidene-1,2-diaminoethane, has been synthesized and characterized by variable-temperature magnetic susceptibility measurement. The complex exhibits ferromagnetic coupling between the oxalato-bridged copper atoms and antiferromagnetic coupling between the oxygen-bridged copper atoms.

引用

页码：4265 / 4267

页数：3

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