Time evolution of near membrane layers

被引:23
作者
Dworecki, K
Kosztolowicz, T
Mrówczynski, S
Wasik, S
机构
[1] Jan Kochanowski Univ Humanities & Sci, Inst Phys, PL-25406 Kielce, Poland
[2] Soltan Inst Nucl Studies, PL-00681 Warsaw, Poland
关键词
D O I
10.1007/s101890070009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The near membrane layer is a region where the concentration of the substance transported across the membrane is significantly decreased. Its thickness is defined as a length over which the concentration drops k times with k being an arbitrary large number. The time evolution of such a layer is studied experimentally by means of the laser interferometric method. It is shown that within the experimental errors the thickness of the near membrane layer grows in time for any k as a roott with the coefficient a being independent of the initial concentration and the membrane permeability. Time evolution of the near membrane layers is also analyzed theoretically. The regularities found experimentally are naturally described within the model which has been earlier developed by one of us. In particular, a scales as erfc(-1) (1/k).
引用
收藏
页码:389 / 394
页数:6
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