Pd2+•••O3SR- interaction encourages anion encapsulation of a quadruply-stranded Pd complex to achieve chirality or high solubility

被引：41

作者：

Sekiya, Ryo ^{[1
]}

Kuroda, Reiko ^{[1
]}

机构：

[1] Univ Tokyo, Dept Life Sci, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 45期

基金：

日本科学技术振兴机构;

关键词：

PALLADIUM(II); ION;

D O I：

10.1039/c1cc14982b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pd2+center dot center dot center dot O3SR- and CH center dot center dot center dot O3SR- interactions were found to play a crucial role in the encapsulation of organic sulfonates in a quadruply-stranded complex of Pd2L4-type. We have successfully employed this feature to achieve chirality induction by complexation with chiral guests as well as solubility increase by dendronization.

引用

页码：12346 / 12348

页数：3

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