The oxidation of aromatic aldehydes by magnesium monoperoxyphthalate and urea-hydrogen peroxide

被引:60
作者
Heaney, H [1 ]
Newbold, AJ [1 ]
机构
[1] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England
关键词
D O I
10.1016/S0040-4039(01)01332-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Magnesium monoperoxyphthalate and urea-hydrogen peroxide-acetic anhydride are effective reagents in the oxidation of benzaldehyde to benzoic acid and o- and p-methoxybenzaldehyde to the corresponding phenols. On the other hand, aromatic aldehydes, including the isomeric methoxybenzaldehydes, are oxidised to the corresponding benzoic acid derivatives in good to excellent yields by the hydroperoxide anion generated from Urea-hydrogen peroxide. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6607 / 6609
页数:3
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