Palladium(II)-selenoether complexes as new single source precursors: First synthesis of Pd4Se and Pd7Se4 nanoparticles

被引：46

作者：

Singh, Ved Vati ^{[1
]}

Rao, Gyandshwar Kumar ^{[1
]}

Kumar, Arun ^{[1
]}

Singh, Ajai K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, New Delhi 110016, India

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 04期

关键词：

HECK REACTION; PLATINUM(II) COMPLEXES; COUPLING REACTIONS; SCHIFF-BASES; SPECTROSCOPY; CHEMISTRY; SELENIDE; TRANSFORMATION; CHALCOGENIDES; CATALYSTS;

D O I：

10.1039/c2dt12113a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd4Se and Pd7Se4 nanoparticles (size 38-104 nm), protected by TOP, have been obtained for the first time using Pd(II) ligated with selenated primary and secondary amines (see 1 and 2) as single source precursors respectively. TEM, SEM, powder XRD and photoluminescence have been used to characterize them. 1 and 2 are also the first Pd(II)-selenoether complexes used for the synthesis of nanoparticles containing palladium and selenium.

引用

页码：1142 / 1145

页数：4

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