Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide:: the X-ray structure of (1S,2R,6R,8R)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl-5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine

被引：0

作者：

Kolesnik, VD

Rybalova, TV

Gatilov, YV

Tkachev, AV ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2001年 / 03期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of dibenzylphosphine oxide with myrtenoic acid nitrile in tert-butyl methyl ether in the presence of sodium hydride results in the formation of substituted aminophospholene oxide in good yield (83%).

引用

页码：98 / U3

页数：2

共 50 条

[31] Crystal structure of (1R,2S,5S,6R,7R)-6-(4-bromobenzenesulfonyloxy)methyl-2,7-dimethyl-tricyclo[5.2.2.01,5]undec-8-ene, C20H25BrO3
Kirfel, A
Euler, H
Valder, C
Neugebauer, A
Meier, M
Braun, NA
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (04): : 539 - 540
[32] ISOLATION FROM ALEXA-LEIOPETALA AND X-RAY CRYSTAL-STRUCTURE OF ALEXINE, (1R,2R,3R,7S,8S)-3-HYDROXYMETHYL-1,2,7-TRIHYDROXYPYRROLIZIDINE [(2R,3R,4R,5S,6S)-2-HYDROXYMETHYL-1-AZABICYCLO[3.3.0]OCTAN-3,4,6-TRIOL], A UNIQUE PYRROLIZIDINE ALKALOID
NASH, RJ
FELLOWS, LE
DRING, JV
FLEET, GWJ
DEROME, AE
HAMOR, TA
SCOFIELD, AM
WATKIN, DJ
TETRAHEDRON LETTERS, 1988, 29 (20) : 2487 - 2490
[33] (1R,3S,6S)-6-tert-Butyl-1-hydroxymethyl-5-methoxy-6-methyl-7-oxa-4-azaspiro[2.5]oct-4-en-8-one and dimethyl[(1S,1R′,3S′,6S′)-(6′-tert-butyl-5′-methoxy-6′-methyl-8′-oxo-7′-oxa-4′-azaspiro[2.5]oct-4′-en-1′-yl)hydroxymethyl]phosphonate
Malecka, M
Wanner, KT
Budzisz, E
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 : O317 - O320
[34] Synthesis of chiral organotin reagents: synthesis of diphenyl{(1S,2R,3S,4R)-3(alkoxymethyl)bicyclo[2.2.1]h eptan$ MIN@2-yl}-tin hydrides. X-Ray crystal structure of (R)-4,4-dimethyl-2-oxotetrahydrofuran-3-yl (1S,2S,3R,4R)-3-triphenylstannylbicyclo[2.2.1]hept-5- ene-2-carboxylate
Beddoes, R. L.
Pratt, R. M.
Thomas, E. J.
Jornal of the Chemical Society. Perkin Transactions 1, (04):
[35] TRICYCLIC PRODUCTS FROM THE REACTION BETWEEN PENICILLIN DERIVED THIAZOLOAZETIDINONES AND ETHYL DIAZOACETATE - X-RAY STRUCTURE OF METHYL 2-[(1R, 3S, 4R, 5S, 6S, 8R)-3-BENZYL-4,5-BISMETHOXYCARBONYL-6-ETHOXY-CARBONYL-9-OXO-7,10-DIAZA-2-THIATRICYCLO[6.2.0.0(3,7)]DECAN-10-YL]-3-METHYLBUT-2-ENOATE
MARA, AM
SINGH, O
THOMAS, EJ
WILLIAMS, DJ
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1982, (09): : 2169 - 2173
[36] THE 3,4-DIHYDRO-2H-PYRAN APPROACH TO (+)-MILBEMYCIN-BETA-3 .2. AN IMPROVED SYNTHESIS OF (2R,4S,6S,8R,9S)-2-[(5R)-(2E)-3-METHYL-5-FORMYL-HEX-2-EN-1-YL]-8,9-DIMETHYL-4-(DIMETHYL-TERT-BUTYLSILYLOXY)-1,7-DIOXA-SPIRO[5.5]UNDECANE
KOCIENSKI, PJ
STREET, SDA
YEATES, C
CAMPBELL, SF
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (10): : 2189 - 2194
[37] Crystal structure of tert-butyl (-)-(1S,5R,8R,4'S)-8-(2',2'-dimethyl-1',3'-dioxolan-4'-yl)-2,6-dioxobicyclo[3.2.1]octane-1-carboxylate, C18H26O6
Peters, K
Peters, EM
Braun, NA
Spitzner, D
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (12): : 963 - 964
[38] Crystal structure of [4S-[3(2R*,3Z,5R*),4R*]]-3-[2,5-bis(acetyloxy)-1-oxo-3-hexenyl]-2,2-diemthyl-4-phenyl-oxazolidine, [C6H7O(OCOCH3)2][C3H3NO(CH3)2C6H5]
Peters, K
Peters, EM
Güthlein, M
Wirth, T
Adam, W
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2000, 215 (03): : 383 - 384
[39] APPROACHES TO THE ASSEMBLY OF THE ANTIFUNGAL AGENT FR-900848 - STUDIES ON THE ASYMMETRIC-SYNTHESIS OF BICYCLOPROPANES AND AN X-RAY CRYSTALLOGRAPHIC ANALYSIS OF (4R,5R)-2-[(1R,3S,4S,6R)-6-PHENYL-1-BICYCLOPROPYL]-1,3-DIMETHYL-4,5-DIPHENYLIMIDAZOLIDINE (VOL 15, PG 1783, 1994)
BARRETT, AGM
DOUBLEDAY, WW
TUSTIN, GJ
WHITE, AJP
WILLIAMS, DJ
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (23) : 2739 - 2739
[40] Spectroscopic, thermal and X-ray powder diffraction patterns of Bi(V) complexes with [2S-[2α, 5α, 6β(S*)]-6-[amino(4-hydroxyphenyl) acetylamino]-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3,2,0] hepatane-2-carboxylic acid and (6R)-6-(α-phenyl-D-glycyamino) penicillinic acids
Kumar, Rajiv
Mishra, Parashuram
MAIN GROUP CHEMISTRY, 2008, 7 (01) : 1 - 14

← 1 2 3 4 5 →

Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide:: the X-ray structure of (1S*,2R*,6R*,8R*)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl-5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine

Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide:: the X-ray structure of (1S,2R,6R,8R)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl-5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine