DNA-mediated electron transfer

被引：49
作者：
Priyadarshy, S
Risser, SM
Beratan, DN [1 ]
机构：
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
[2] Texas A&M Commerce, Dept Phys, Commerce, TX 75429 USA
来源：
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY | 1998年 / 3卷 / 02期
关键词：
electron transfer; Pi-way; tunneling pathway; hole transfer; tunneling energy;
D O I：
10.1007/s007750050221
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Electron transfer in DNA has been investigated for decades, but recent experiments highlight our limited fundamental understanding of these processes. Modern electron transfer theory may help to address some of the open mechanistic issues, We summarize and analyze the results of recent experiments from a theoretical perspective. Future research directions are suggested that might help to establish the molecular mechanism(s) for long-range DNA electron transfer.
引用
收藏
页码：196 / 200
页数：5
相关论文
共 30 条
[1]   Rates of DNA-mediated electron transfer between metallointercalators [J].
Arkin, MR ;
Stemp, EDA ;
Holmlin, RE ;
Barton, JK ;
Hormann, A ;
Olson, EJC ;
Barbara, PF .
SCIENCE, 1996, 273 (5274) :475-480
[2]  
BAKSHI AK, 1994, PROG BIOPHYS MOL BIO, V61, P187
[3]  
Bensasson R.V., 1993, EXCITED STATES FREE
[4]   DNA: Insulator or wire? [J].
Beratan, DN ;
Priyadarshy, S ;
Risser, SM .
CHEMISTRY & BIOLOGY, 1997, 4 (01) :3-8
[5]  
Bertini I., 1994, Bioinorganic Chemistry, DOI 10/BioinCh_chapter9.pdf
[6]   ENERGY-TRANSFER AND ELECTRON-TRANSFER PROCESSES INVOLVING PALLADIUM PORPHYRINS BOUND TO DNA [J].
BRUN, AM ;
HARRIMAN, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (23) :10383-10393
[7]   Oxidative thymine dimer repair in the DNA helix [J].
Dandliker, PJ ;
Holmlin, RE ;
Barton, JK .
SCIENCE, 1997, 275 (5305) :1465-1468
[8]   INTERCALATION COMPOUNDS OF GRAPHITE [J].
DRESSELHAUS, MS ;
DRESSELHAUS, G .
ADVANCES IN PHYSICS, 1981, 30 (02) :139-326
[9]  
Fukui K, 1998, ANGEW CHEM INT EDIT, V37, P158, DOI 10.1002/(SICI)1521-3773(19980202)37:1/2<158::AID-ANIE158>3.3.CO
[10]  
2-C
123