Rhodium-catalyzed decomposition of indole-substituted α-diazo-β-keto esters:: three different reactions based on indole oxidation state

被引：75

作者：

Jung, ME ^{[1
]}

Slowinski, F ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 39期

基金：

澳大利亚研究理事会;

关键词：

rhodium(II)-catalyzed reactions of diazo esters; cyclopropanation of indole double bond; oxindole reaction with carbenoids; oxidation of indoline to indole using carbenoid;

D O I：

10.1016/S0040-4039(01)01431-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium(II)-catalyzed decomposition of three indole-substituted alpha -diazo-beta -keto esters affords three different types of intramolecular reactions based on the oxidation state of the indole. (C) 2001 Published by Elsevier Science Ltd.

引用

页码：6835 / 6838

页数：4

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