Heliannuol: Distribution, Biological Activities, 1H and 13C-NMR Spectral Data

被引:3
作者
Rocha Ribeiro, Carlos Magno [1 ]
Galvao de Souza, Thiago Silva [1 ]
de Almeida, Karinne Canevalli [1 ]
Borba Dutra, Karen Danielle [1 ]
Valverde, Alessandra Leda [1 ]
机构
[1] Univ Fed Fluminense, Dept Quim Organ, Niteroi, RJ, Brazil
关键词
H-1 and C-13-NMR spectral data; biological activities; distribution; gorgonian; heliannuols; sunflower; ENANTIOSELECTIVE TOTAL-SYNTHESIS; SUNFLOWER LEAVES; BIOACTIVE SESQUITERPENE; (+/-)-HELIANNUOL D; NATURAL-PRODUCTS; EFFICIENT; ALLELOCHEMICALS; HELIANANE; ROUTE; PSEUDOPTEROGORGIA;
D O I
10.2174/1570193X16666190405102658
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Heliannuols are an important class of compounds isolated from Helianihus armors, common sunflower, with allelopathic properties. Interestingly, two of these fourteen compounds have been isolated from a gorgonian, Pseudopierogorgia rigida. This review compiles data on the isolation and biological activity of heliannuols described in the literature and briefly reports the papers describing their syntheses. This review could stimulate research into other natural species and syntheses. Further, it describes the H-1 and C-13-NMR spectral data described in the literature for the 14 heliannuols already isolated and correlates them with their respective structures. Therefore, we believe that these searchable data enable a rapid identification in routine analysis of the crude extracts of sunflowers or gorgonians.
引用
收藏
页码:309 / 322
页数:14
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