Synthesis and structural characterisation of [Pd-2(mu-Br)(2)(PBu(t)(3))(2)], an example of a palladium(I)-palladium(I) dimer

被引：90

作者：

Vilar, R

Mingos, DMP

Cardin, CJ

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV READING,DEPT CHEM,READING RG4 9BB,BERKS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 23期

关键词：

D O I：

10.1039/dt9960004313

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses, spectroscopic characterisation and in one case (X = Br) the single-crystal structure of the novel Pd-I-Pd-I dimers [Pd-2(mu-X)(2)(PBu(3)(t))(2)] (X = Br or I) have been determined; preliminary results on their reactions with CO, H-2, CNC(6)H(3)Me(2) and C2H2 have also been obtained.

引用

收藏

页码：4313 / 4314

页数：2

相关论文

共 19 条

[1] INTIMATE MECHANISM OF OXIDATIVE ADDITION TO ZEROVALENT PALLADIUM COMPLEXES IN THE PRESENCE OF HALIDE-IONS AND ITS RELEVANCE TO THE MECHANISM OF PALLADIUM-CATALYZED NUCLEOPHILIC SUBSTITUTIONS [J].

AMATORE, C ;

JUTAND, A ;

SUAREZ, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) :9531-9541

[2] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [PD-4(MU(3)-CH)(MU-CL)(3)(PBU(3)(T))(4)] - A TETRAHEDRAL PALLADIUM CLUSTER-WITH A MU(3)-METHYLIDYNE LIGAND [J].

BURROWS, AD ;

MINGOS, DMP ;

MENZER, S ;

VILAR, R ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (12) :2107-2108

[3] PREPARATION AND FACILE INTRA-MOLECULAR METALATION REACTIONS OF BIS(TRI-T-BUTYLPHOSPHINE)PLATINUM(II) HYDRIDES [J].

CLARK, HC ;

GOEL, AB ;

GOEL, RG ;

OGINI, WO .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (01) :C16-C18

[4]

DUCRUIX A, 1977, ACTA CRYSTALLOGR B, V33, P3688, DOI 10.1107/S0567740877011868

[5] DIMERIC PALLADIUM(I) COMPLEXES CONTAINING BRIDGING CYCLOPENTADIENYL GROUP [J].

FELKIN, H ;

TURNER, GK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 129 (03) :429-436

[6] REACTIONS OF TRI-TERT-BUTYLPHOSPHINE WITH PLATINUM(II) AND PALLADIUM(II) - FACILE INTRAMOLECULAR METALATION OF TRI-TERT-BUTYLPHOSPHINE [J].

GOEL, RG ;

MONTEMAYOR, RG .

INORGANIC CHEMISTRY, 1977, 16 (09) :2183-2186

[7] AUTOMATIC PROCESSING OF ROTATION DIFFRACTION DATA FROM CRYSTALS OF INITIALLY UNKNOWN SYMMETRY AND CELL CONSTANTS [J].

KABSCH, W .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 :795-800

[8]

KELLER E, 1987, SCHAKAL

[9] New insights into structures, stability, and bonding of mu-allyl ligands coordinated with Pd-Pd and Pd-Pt fragments [J].

Kurosawa, H ;

Hirako, K ;

Natsume, S ;

Ogoshi, S ;

Kanehisa, N ;

Kai, Y ;

Sakaki, S ;

Takeuchi, K .

ORGANOMETALLICS, 1996, 15 (08) :2089-2097

[10]

MCPARTLIN M, UNPUB