Young and Young-Laplace equations for a static ridge of nematic liquid crystal, and transitions between equilibrium states

被引:8
作者
Cousins, Joseph R. L. [1 ,2 ]
Duffy, Brian R. [1 ]
Wilson, Stephen K. [1 ]
Mottram, Nigel J. [1 ,2 ]
机构
[1] Univ Strathclyde, Dept Math & Stat, 26 Richmond St, Glasgow G1 1XH, Scotland
[2] Univ Glasgow, Sch Math & Stat, Univ Pl, Glasgow G12 8QQ, Scotland
来源
PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2022年 / 478卷 / 2259期
基金
英国工程与自然科学研究理事会;
关键词
nematic liquid crystals; wetting; dewetting; Young equation; Young-Laplace equation; ISOTROPIC INTERFACE; ANCHORING STRENGTH; FILMS; SURFACE; PHASE; STABILITY; ALIGNMENT;
D O I
10.1098/rspa.2021.0849
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Motivated by the need for greater understanding of systems that involve interfaces between a nematic liquid crystal, a solid substrate and a passive gas that include nematic-substrate-gas three-phase contact lines, we analyse a two-dimensional static ridge of nematic resting on a solid substrate in an atmosphere of passive gas. Specifically, we obtain the first complete theoretical description for this system, including nematic Young and Young-Laplace equations, and then, making the assumption that anchoring breaking occurs in regions adjacent to the contact lines, we use the nematic Young equations to determine the continuous and discontinuous transitions that occur between the equilibrium states of complete wetting, partial wetting and complete dewetting. In particular, in addition to continuous transitions analogous to those that occur in the classical case of an isotropic liquid, we find a variety of discontinuous transitions, as well as contact-angle hysteresis, and regions of parameter space in which there exist multiple partial wetting states that do not occur in the classical case.
引用
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页数:24
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