THE SORPTIVE PERFORMANCE OF MICROORGANISMS-ZEOLITE SYSTEMS TO REMOVE Cu2+, Zn2+, Cd2+, Fe2+ AND Pb2+

被引:0
作者
Peter, Anca [1 ]
Marian, Monica [1 ]
Nicula, Camelia [1 ]
Mihaly-Cozmuta, Leonard [1 ]
Mihaly-Cozmuta, Anca [1 ]
Indrea, Emil [2 ]
机构
[1] N Univ Baia Mare, Fac Sci, Dept Biol Chem, RO-430083 Baia Mare, Romania
[2] Natl Inst Res & Dev Isotop & Mol Technol, RO-400293 Cluj Napoca, Romania
关键词
metal ions; sorption kinetics modeling; microorganisms and microorganisms-zeolite systems; HEAVY-METAL REMOVAL; BIOSORPTION; CLINOPTILOLITE; POPULATIONS; SUPPORTS; CARBON; WATER; IONS;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The adsorption of Cu2+, Zn2+, Cd2+, Fe2+ and Pb2+ on three types of systems (microorganisms, microorganisms-zeolite, and zeolite) has been investigated. Experimental data have been analyzed by kinetic models including the pseudo-first order, the pseudo-second order and Elovich equations. The film and pore diffusion coefficients were also calculated. The studied ions are desorbed from the microorganisms-systems, after 72 hours, excepting Pb2+ which remains adsorbed on bacteria and yeasts systems. The pseudo-second-order equation provides a good fitting to the experimental data points obtained from metal ions adsorption on microorganisms-zeolite and zeolite systems. The zeolite modified with fungi is a more efficient adsorbent than bacteria-zeolite, yeast-zeolite or zeolite for Cd2+. Cu2+, Zn2+ and Fe2+ were adsorbed with the highest rate by the yeast-zeolite system and Pb2+ was adsorbed more efficiently by the bacteria-zeolite system. The adsorption of Cu2+, Cd2+ and Pb2+ onto microorganism-zeolite systems occurs by chemisorption.
引用
收藏
页码:847 / 852
页数:6
相关论文
共 23 条
[1]  
[Anonymous], 1989, HANDLINGAR
[2]   Sorption of Cu2+, Cd2+, and Pb2+ using modified zeolite from coal fly ash [J].
Apiratikul, Ronbanchob ;
Pavasant, Prasert .
CHEMICAL ENGINEERING JOURNAL, 2008, 144 (02) :245-258
[3]   Use of clinoptilolite for the removal of nickel ions from water: Kinetics and thermodynamics [J].
Argun, Mehmet Emin .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 150 (03) :587-595
[4]   Influence of red mud, zeolite and lime on heavy metal immobilization, culturable heterotrophic microbial populations and enzyme activities in a contaminated soil [J].
Garau, Giovanni ;
Castaldi, Paola ;
Santona, Laura ;
Deiana, Pietrino ;
Melis, Pietro .
GEODERMA, 2007, 142 (1-2) :47-57
[5]   A computational study of CO2, N2, and CH4 adsorption in zeolites [J].
Garcia-Perez, E. ;
Parra, J. B. ;
Ania, C. O. ;
Garcia-Sanchez, A. ;
Van Baten, J. M. ;
Krishna, R. ;
Dubbeldam, D. ;
Calero, S. .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2007, 13 (5-6) :469-476
[6]   Removal of heavy metals from the environment by biosorption [J].
Gavrilescu, M .
ENGINEERING IN LIFE SCIENCES, 2004, 4 (03) :219-232
[7]   Lead removal from aqueous solution by natural and pretreated clinoptilolite:: Adsorption equilibrium and kinetics [J].
Gunay, Ahmet ;
Arslankaya, Ertan ;
Tosun, Ismail .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 146 (1-2) :362-371
[8]   Biosorption of copper and lead ions by waste beer yeast [J].
Han, Runping ;
Li, Hongkui ;
Li, Yanhu ;
Zhang, Jinghua ;
Xiao, Huijun ;
Shi, Jie .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (03) :1569-1576
[9]   Biosorption mechanism of nine different heavy metals onto biomatrix from rice husk [J].
Krishnani, Kishore K. ;
Meng, Xiaoguang ;
Christodoulatos, C. ;
Boddu, Veera M. .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 153 (03) :1222-1234
[10]   Impact of cell wall structure on the behavior of bacterial cells as sorbents of cadmium and lead [J].
Kulczycki, E ;
Ferris, FG ;
Fortin, D .
GEOMICROBIOLOGY JOURNAL, 2002, 19 (06) :553-565