The polymeric copper(II) complex, 2,2'-bipyridine-N,N'-(mu-nicotinato-O,O':N) monoaquacopper (II) nitrate dihydrate

被引：27

作者：

Xu, DJ ^{[1
]}

Xie, AL ^{[1
]}

Xu, YZ ^{[1
]}

Zhang, CG ^{[1
]}

Chen, WG ^{[1
]}

机构：

[1] HANGZHOU UNIV,DEPT CHEM,HANGZHOU 310028,PEOPLES R CHINA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1996年 / 39卷 / 3-4期

基金：

美国国家科学基金会;

关键词：

nicotinate bipyridyl; copper(II); crystal structure;

D O I：

10.1080/00958979608024335

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nicotinate complex of Cu(II), 2,2'-bipyridine(nicotinato)monoaquacopper(II) nitrate dihydrate has been prepared and its crystal structure has been determined by means of X-ray methods. The nicotinate anions bridge adjacent Cu(II) atoms through both the pyridine N atom and the carboxyl group to form infinite chains. The carboxyl group of the nicotinate anion coordinates to the Cu(II) atom as a chelate. Based on the molecular structure the infrared spectrum is discussed.

引用

页码：273 / 280

页数：8

共 20 条

[1] SOME 1ST ROW TRANSITION-METAL COMPLEXES OF NICOTINAMIDE AND NICOTINIC-ACID [J].