Glass-Crystal Growth Mode for Testosterone Propionate

被引:64
作者
Shtukenberg, Alexander [1 ]
Freundenthal, John [1 ]
Gunn, Erica [2 ]
Yu, Lian [2 ]
Kahr, Bart [1 ]
机构
[1] NYU, Dept Chem, New York, NY 10003 USA
[2] Univ Wisconsin, Sch Pharm, Madison, WI 53705 USA
基金
美国国家科学基金会;
关键词
NUCLEATION-BASED CRYSTALLIZATION; O-TERPHENYL; TRANSITION; MECHANISM; LIQUID;
D O I
10.1021/cg200640g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The recently discovered glass-crystal (GC) growth mode in some glass-forming liquids is characterized by strong and abrupt growth rate enhancement just in the vicinity of the glass transition temperature. GC growth previously has been observed in only 10 compounds. The data on testosterone propionate presented here indicate the fastest GC growth acceleration observed to date. Moreover, testosterone propionate is the first compound to show a helically twisted morphology concomitant with GC growth. It has been previously stated that an aryl ring is a prerequisite of GC growth, but testosterone propionate obviates that claim.
引用
收藏
页码:4458 / 4462
页数:5
相关论文
共 50 条
  • [1] Ductility of an ultrastrong glass-crystal nano-dual-phase alloy in sub-micron
    Wu, Ge
    Zhang, Jiayong
    Liu, Chang
    Wang, Qing
    Lu, Jian
    SCRIPTA MATERIALIA, 2020, 183 : 17 - 21
  • [2] Thermodynamic properties of vitreous electrodes in a Ni/NiP glass-crystal Galvanic cell
    Jordanov, Nicolai
    Wondraczek, Lothar
    Gutzow, Ivan
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2013, 382 : 125 - 132
  • [3] Glass-crystal transformations in Se80-xTe20Agx (x=0, 3, 5, 7 and 9) glasses
    Naqvi, S. Faheem
    Deepika
    Saxena, N. S.
    Sharma, Kananbala
    Bhandari, D.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 506 (02) : 956 - 962
  • [4] Orientation dependences of atomic structures in chemically heterogeneous Cu50Ta50/Ta glass-crystal interfaces
    Yang, Guiqin
    Gao, Xiaoze
    Li, Jinfu
    Kong, Lingti
    JOURNAL OF APPLIED PHYSICS, 2015, 117 (01)
  • [5] Near-ideal strength and large compressive deformability of a nano-dual-phase glass-crystal alloy in sub-micron
    Wu, Ge
    Sun, Ligang
    Zhu, Linli
    Liu, Chang
    Wang, Qing
    Bao, Yan
    Lu, Jian
    SCRIPTA MATERIALIA, 2020, 188 : 290 - 295
  • [6] Fast crystal growth in glass-forming liquids
    Orava, J.
    Greer, A. L.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2016, 451 : 94 - 100
  • [7] Growth mode of helium crystal near dislocations in titanium
    Zhang, Bao-Ling
    Wang, Bao-Wen
    Su, Xue
    Song, Xiao-Yong
    Li, Min
    CHINESE PHYSICS B, 2018, 27 (06)
  • [8] Decelerated crystal growth in a soda-lime-silica glass
    Fielitz, Peter
    Cassar, Daniel R.
    Yuritsyn, Nikolay S.
    Abyzov, Alexander S.
    Fokin, Vladimir M.
    Borchardt, Guenter
    Deubener, Joachim
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2022, 596
  • [9] Ultrafast spherulitic crystal growth as a stress-induced phenomenon specific of fragile glass-formers
    Caroli, Christiane
    Lemaitre, Anael
    JOURNAL OF CHEMICAL PHYSICS, 2012, 137 (11)
  • [10] Crystal growth nucleation and Fermi energy equalization of intrinsic spherical nuclei in glass-forming melts
    Tournier, Robert F.
    SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2009, 10 (01)