Polyhedral boron clusters in materials science

被引:175
作者
Dash, Barada Prasanna [1 ]
Satapathy, Rashmirekha [1 ]
Maguire, John A. [2 ]
Hosmane, Narayan S. [1 ]
机构
[1] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA
[2] So Methodist Univ, Dept Chem, Dallas, TX 75275 USA
基金
美国国家科学基金会;
关键词
WALLED CARBON NANOTUBES; NONLINEAR-OPTICAL MATERIALS; CONTAINING LIQUID-CRYSTALS; IRON-OXIDE NANOPARTICLES; CHARGED AROMATIC DONORS; P-CARBORANES; ICOSAHEDRAL CARBORANES; COORDINATION POLYMERS; MESOGENIC PROPERTIES; DRUG-DELIVERY;
D O I
10.1039/c1nj20228f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Robust three-dimensional structure, aromaticity, high chemical and thermal stability of polyhedral boron clusters make them promising candidates for use in materials science. Boron clusters have been used for the synthesis of luminescent materials, polymers, coordination polymers or metal-organic frameworks, dendrimers, liquid crystals, and nonlinear optical materials. Some of these clusters have been used as molecular building blocks in nanoscience. This review summarizes the applications of polyhedral boron clusters in materials science.
引用
收藏
页码:1955 / 1972
页数:18
相关论文
共 187 条
[1]   A new class of carborane compounds for second-order nonlinear optics:: Ab initio molecular orbital study of hyperpolarizabilities for 1-(1′,X′-dicarba-closo-dodecaborane-1′-yl)-closo-dodecaborate dianion (X = 2,7,12) [J].
Abe, J ;
Nemoto, N ;
Nagase, Y ;
Shirai, Y ;
Iyoda, T .
INORGANIC CHEMISTRY, 1998, 37 (02) :172-173
[2]   Group 1 coordination chains and hexagonal networks of host cyclotriveratrylene with halogenated monocarbaborane anions [J].
Ahmad, R ;
Franken, A ;
Kennedy, JD ;
Hardie, ML .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (09) :2190-2198
[3]   Variable Ag(I) coordination modes in silver cobalt(III) bis(dicarbollide) supramolecular assemblies with cyclotriveratrylene host molecules [J].
Ahmad, R ;
Hardie, MJ .
CRYSTAL GROWTH & DESIGN, 2003, 3 (04) :493-499
[4]   Hydrogen-bonded superstructures of a small host molecule and lanthanide aquo ions [J].
Ahmad, R ;
Dix, I ;
Hardie, MJ .
INORGANIC CHEMISTRY, 2003, 42 (07) :2182-2184
[5]   3-DIMENSIONAL AROMATICITY OF POLYHEDRAL BORANES [J].
AIHARA, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (11) :3339-3342
[6]   Magnetic drug targeting - Biodistribution of the magnetic carrier and the chemotherapeutic agent mitoxantrone after locoregional cancer treatment [J].
Alexiou, C ;
Jurgons, R ;
Schmid, RJ ;
Bergemann, C ;
Henke, J ;
Erhardt, W ;
Huenges, E ;
Parak, F .
JOURNAL OF DRUG TARGETING, 2003, 11 (03) :139-149
[7]  
Alexiou C, 2000, CANCER RES, V60, P6641
[8]   Convection-enhanced delivery of nanocarriers for the treatment of brain tumors [J].
Allard, Emilie ;
Passirani, Catherine ;
Benoit, Jean-Pierre .
BIOMATERIALS, 2009, 30 (12) :2302-2318
[9]   Polyhedral-based nonlinear optical materials. 2. Theoretical investigation of some new high nonlinear optical response compounds involving polyhedral bridges with charged aromatic donors and acceptors [J].
Allis, DG ;
Spencer, JT .
INORGANIC CHEMISTRY, 2001, 40 (14) :3373-3380
[10]   Polyhedral-based nonlinear optical materials. Part 1. Theoretical investigation of some new high nonlinear optical response compounds involving carboranes and charged aromatic donors and accepters [J].
Allis, DG ;
Spencer, JT .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 614 :309-313