Hybrid salts of binuclear Bi(III) halide complexes with 1,2-bis (pyridinium)ethane cation: Synthesis, structure and luminescent behavior

被引：45

作者：

Adonin, Sergey A. ^{[1
,2
]}

Rakhmanova, Marianna I. ^{[1
]}

Samsonenko, Denis G. ^{[1
,2
]}

Sokolov, Maxim N. ^{[1
,2
]}

Fedin, Vladimir P. ^{[1
,2
]}

机构：

[1] SB RAS, Nikolaev Inst Inorgan Chem, Lavrentiev Ave 3, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia

来源：

INORGANICA CHIMICA ACTA | 2016年 / 450卷

基金：

俄罗斯科学基金会;

关键词：

Bismuth; Halide complexes; Luminescence; p-Block metals; X-ray diffractometry; BIDENTATE BASE SYSTEMS; CRYSTAL-STRUCTURE; VIBRATIONAL PROPERTIES; BISMUTH(III) CHLORIDE; DIELECTRIC-PROPERTIES; OPTICAL-PROPERTIES; MOLECULAR MOTIONS; PHASE-TRANSITIONS; VIOLOGEN; COMPOUND;

D O I：

10.1016/j.ica.2016.06.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between 1,2-bis(pyridinium)ethane bromide ((BPE)Br-2) and [ BiCl6](3)/[ BiBr6](3) in HCl or HBr results in isostructural binuclear complexes (BPE)(2)[Bi2X10] (X = Cl (1) and Br (2)) which were characterized by X-ray diffractometry, IR and Raman spectroscopy. Both complexes manifest orange-red luminescence in solid state. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：232 / 235

页数：4

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