Electrochemical oxidation behavior of hydroxypivalaldehyde in the ionic liquids

被引：8

作者：

Jian Fang Zhong ^{[1
]}

De Liang He ^{[1
]}

Zhou Zhou ^{[1
]}

Yi Bin Xu ^{[1
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2008年 / 19卷 / 03期

关键词：

hydroxypivalaldehyde; ILs; cyclic voltammetry; chronocoulometry;

D O I：

10.1016/j.cclet.2007.12.017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The similar electrochemical oxidation behaviors of hydroxypivalaldehyde in ionic liquids (ILs) medium, C4MIMPF6, C4MIMBF4 and C8MIWF6, are investigated using classic electrochemical methods, respectively. Only the product, hydroxypivalic acid is detected by high performance liquid chromatography (HPLC). It can be conferred that the electrochemical oxidation of hydroxypivalaldehyde consists of two successive one-electron irreversible reactions at glass carbon (GC) electrode and the possible reaction mechanism in the ILs is proposed firstly. The diffusion coefficients of hydroxypivalaldehyde are obtained according to the electrochemical characteristics of hydroxypivalaldehyde in C4MIWF6, C4MIMBF4 and C8N4IMPF6. (c) 2007 De Liang He. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：319 / 323

页数：5

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