Carbon Supported Phosphoric Acid Catalysts for Gas-Phase Synthesis of Diesel Additives

被引：9
作者：
Gruenert, Anna [1 ]
Schmidt, Wolfgang [1 ]
Schueth, Ferdi [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany
来源：
CATALYSIS LETTERS | 2020年 / 150卷 / 10期
关键词：
POLYOXYMETHYLENE DIMETHYL ETHERS; CHEMICAL-EQUILIBRIUM; EFFICIENT SYNTHESIS; REACTION-KINETICS; IONIC LIQUIDS; FORMALDEHYDE; METHANOL; PERFORMANCE; OME;
D O I：
10.1007/s10562-020-03200-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Carbon supported phosphoric acid (H3PO4/C) was found to be a more productive catalyst for the gas-phase synthesis of the diesel fuel additive/substitute oxymethylene ethers (OME) as compared to benchmark zeolite catalysts. In this contribution, the performance of catalysts H3PO4/C and related H2PO4-/C and HPO42-/C materials in OME synthesis from methanol and formaldehyde is described. [GRAPHICS]
引用
收藏
页码：2951 / 2958
页数：8
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