Singlet oxygen in the heterogeneous catalytic oxidation of benzene

被引：10
|
作者：
Boikov, E. V. [1 ]
Vishnetskaya, M. V. [1 ]
Emel'yanov, A. N. [1 ]
Rufov, Yu. N. [2 ]
Shcherbakov, N. V. [1 ]
Tomskii, I. S. [1 ]
机构：
[1] Gubkin State Univ Oil & Gas, Moscow 117917, Russia
[2] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2007年 / 81卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1134/S0036024407060052
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The partial oxidation of benzene on vanadium and molybdenum oxides and the participation of singlet oxygen in this reaction were studied. A correlation between the activity of the catalysts in the partial oxidation of benzene and their ability to generate singlet oxygen was observed. The character of the initiation of oxidative benzene transformations under the action of molecular singlet oxygen was analyzed.
引用
收藏
页码：861 / 865
页数：5
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