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Hydrolysis/dehydration/aldol-condensation/hydrogenation of lignocellulosic biomass and biomass-derived carbohydrates in the presence of Pd/WO3-ZrO2 in a single reactor
被引:62
作者:
Dedsuksophon, W.
[1
]
Faungnawakij, K.
[2
]
Champreda, V.
[3
]
Laosiripojana, N.
[1
]
机构:
[1] King Mongkuts Univ Technol Thonburi, Joint Grad Sch Energy & Environm, CHE Ctr Energy Technol & Environm, Thonburi, Thailand
[2] Natl Nanotechnol Ctr NANOTEC, Pathum Thani, Thailand
[3] Natl Ctr Genet Engn & Biotechnol BIOTEC, Pathum Thani, Thailand
关键词:
Lignocellulosic biomass;
Biomass-derived carbohydrate;
Pd/WO3-ZrO2;
Furan;
Alkane;
HOT COMPRESSED WATER;
SOLID ACID;
SUPERCRITICAL WATER;
ALDOL-CONDENSATION;
BASE CATALYSTS;
473;
K;
FRUCTOSE;
GLUCOSE;
DEHYDRATION;
HYDROLYSIS;
D O I:
10.1016/j.biortech.2010.09.073
中图分类号:
S2 [农业工程];
学科分类号:
0828 ;
摘要:
Hydrolysis/dehydration/aldol-condensation/hydrogenation of lignocellulosic-biomass (corncobs) and biomass-derived carbohydrates (tapioca flour) to produce water-soluble C-5-C-15 compounds was developed in a single reactor system. WO3-ZrO2 efficiently catalyzed the hydrolysis/dehydration of these feedstocks to 5-hydroxymethylfurfural and furfural, while the impregnation of WO3-ZrO2 with Pd allowed sequential aldolcondensation/hydrogenation of these furans to C-5-C-15 compounds. The highest C-5-C-15 yields of 14.8-20.3% were observed at a hydrolysis/dehydration temperature of 573 K for 5 min, an aldol-condensation temperature of 353 K for 30 h, and a hydrogenation temperature of 393 K for 6 h. The C-5-C-15 yield from tapioca flour was higher than that from corncobs (20.3% compared to 14.8%). Tapioca flour produced more C-6/C-9/C-15, whereas corncobs generated more C-5/C-8/C-13 compounds due to the presence of hemicellulose in the corncobs. These water-soluble organic compounds can be further converted to liquid alkanes with high cetane numbers for replacing diesel fuel in transportation applications. (C) 2010 Elsevier Ltd. All rights reserved.
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页码:2040 / 2046
页数:7
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