Hydrolysis/dehydration/aldol-condensation/hydrogenation of lignocellulosic biomass and biomass-derived carbohydrates in the presence of Pd/WO3-ZrO2 in a single reactor

被引:62
作者
Dedsuksophon, W. [1 ]
Faungnawakij, K. [2 ]
Champreda, V. [3 ]
Laosiripojana, N. [1 ]
机构
[1] King Mongkuts Univ Technol Thonburi, Joint Grad Sch Energy & Environm, CHE Ctr Energy Technol & Environm, Thonburi, Thailand
[2] Natl Nanotechnol Ctr NANOTEC, Pathum Thani, Thailand
[3] Natl Ctr Genet Engn & Biotechnol BIOTEC, Pathum Thani, Thailand
关键词
Lignocellulosic biomass; Biomass-derived carbohydrate; Pd/WO3-ZrO2; Furan; Alkane; HOT COMPRESSED WATER; SOLID ACID; SUPERCRITICAL WATER; ALDOL-CONDENSATION; BASE CATALYSTS; 473; K; FRUCTOSE; GLUCOSE; DEHYDRATION; HYDROLYSIS;
D O I
10.1016/j.biortech.2010.09.073
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Hydrolysis/dehydration/aldol-condensation/hydrogenation of lignocellulosic-biomass (corncobs) and biomass-derived carbohydrates (tapioca flour) to produce water-soluble C-5-C-15 compounds was developed in a single reactor system. WO3-ZrO2 efficiently catalyzed the hydrolysis/dehydration of these feedstocks to 5-hydroxymethylfurfural and furfural, while the impregnation of WO3-ZrO2 with Pd allowed sequential aldolcondensation/hydrogenation of these furans to C-5-C-15 compounds. The highest C-5-C-15 yields of 14.8-20.3% were observed at a hydrolysis/dehydration temperature of 573 K for 5 min, an aldol-condensation temperature of 353 K for 30 h, and a hydrogenation temperature of 393 K for 6 h. The C-5-C-15 yield from tapioca flour was higher than that from corncobs (20.3% compared to 14.8%). Tapioca flour produced more C-6/C-9/C-15, whereas corncobs generated more C-5/C-8/C-13 compounds due to the presence of hemicellulose in the corncobs. These water-soluble organic compounds can be further converted to liquid alkanes with high cetane numbers for replacing diesel fuel in transportation applications. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2040 / 2046
页数:7
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