Zinc-Catalyzed Domino Hydroamination-Alkyne Addition

被引：32
|
作者：
Biyikal, Mustafa [2 ]
Porta, Marta [2 ]
Roesky, Peter W. [1 ]
Blechert, Siegfried [2 ]
机构：
[1] KIT, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 11-12期
关键词：
alkynes; domino reaction; hydroamination; metathesis; propargylamines; zinc; GAMMA; DELTA-ALKYNYL-BETA-AMINO ACID-DERIVATIVES; ANTI-MARKOVNIKOV HYDROAMINATION; RING-CLOSING METATHESIS; H BOND ACTIVATION; TERMINAL ALKYNES; INTRAMOLECULAR HYDROAMINATION; INTERMOLECULAR HYDROAMINATION; EFFICIENT SYNTHESIS; CASCADE REACTIONS; INCREASED REACTIVITY;
D O I：
10.1002/adsc.201000211
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first zinc-catalyzed one-step synthesis of quaternary propargylamines with four different substituents is described. The domino hydroamination alkyne addition reaction gives access to functionalized propargylamines under mild conditions
引用
收藏
页码：1870 / 1875
页数：6
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