Fujenal, a diterpenoid saga of neighbouring group participation

被引：4
|
作者：
Hanson, James R. [2 ]
Fraga, Braulio M. [1 ]
机构：
[1] CSIC, Inst Prod Nat & Agrobiol, Tenerife 38206, Spain
[2] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England
来源：
PHYTOCHEMISTRY | 2008年 / 69卷 / 11期
关键词：
Gibberella fujikuroi; diterpenoids; fujenal; fujenoic acid; fujenoic triacid; neighbouring group; review;
D O I：
10.1016/j.phytochem.2008.05.009
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The chemistry, the biosynthesis and the biotransformations related to fujenal and its analogues are reviewed. Despite the opportunity for free rotation about the C-9:C-10 bond, the chemistry of the ring B of this diterpenoid is dominated by neighbouring group participation between C-6, C-7 and C-19. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2104 / 2109
页数：6
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