Highly Stable Porous Polymer Networks with Exceptionally High Gas-Uptake Capacities

被引：553
作者：
Yuan, Daqiang [1 ]
Lu, Weigang [1 ]
Zhao, Dan [2 ]
Zhou, Hong-Cai [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA
来源：
ADVANCED MATERIALS | 2011年 / 23卷 / 32期
基金：
美国国家科学基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; HIGH-SURFACE-AREA; POROSITY; STORAGE;
D O I：
10.1002/adma.201101759
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly stable porous polymer networks (PPNs) are synthesized through a Yamamoto homocoupling reaction between tetrahedral monomers. Among those polymers, PPN-4 shows exceptionally high Langmuir surface area of 10063 m(2) g(-1) (SA(BET): 6461 m(2) g(-1)). It also exhibits ultra high hydrogen, methane, and carbon dioxide storage capacities. These properties make it a perfect adsorbent for clean energy applications.
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收藏
页码：3723 / +
页数：4
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